화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korea Polymer Journal, Vol.8, No.5, 231-237, October, 2000
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Polymerization of 3-Ethynylphenol by Transition Metal Catalysts
Yeong Soon Gal†, Won Chul Lee1, Sung Ho Jin2, and Hyung Jong Lee3
  • Polymer Chemistry Laboratory, College of General Education, Kyungil University, Hayang 712-701, Kyungsangbuk-Do, Korea
  • 1Department of Textile and Fashion Technology, Kyungil University, Hayang 712-701, Kyungsangbuk-Do, Korea
  • 2Department of Chemistry Education, Pusan National University, Pusan 609-735, Korea
  • 3Zenphotonics, Rm 303, K-MAC BLD., 104-11 Moonji-Dong, Yusong-Gu, Taejon 305-380, Korea
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The polymerization of 3-ethynylphenol, phenylacetylene having hydroxy functionality, was carried out by tungsten and molybdenum-based transition metal catalysts. The polymerization proceeded to give a moderate yield of polymer. The effects on the mole ratio of monomer to catalyst(M/C), initial monomer concentration ([M]0), and the polymerization temperature for the polymerization of than that of Mo-based catalysts. The resulting polymers were brown or black powders and mostly insoluble in organic solvents. Structural analysis of the polymer by instrumental methods revealed the conjugated polymer backbone structure carrying hydroxyphenyl moieties. Thermal and morphological properties of the resulting poly(3-ethynylphenol) were also discussed.
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