화학공학소재연구정보센터
Journal of Power Sources, Vol.247, 831-839, 2014
Characterization of Ni-YSZ anodes for solid oxide fuel cells fabricated by solution precursor plasma spraying with axial feedstock injection
Nickel and yttria-stabilized zirconia (YSZ) anodes were fabricated by solution precursor plasma spraying (SPPS) and incorporated into metal-supported solid oxide fuel cells (SOFC). A power density of 0.45 W cm(-2) at 0.7 V and a peak power density of 0.52 W cm(-2) at 750 degrees C in humidified H-2 was obtained, which are the first performance results reported for an SOFC having an anode fabricated by SPPS. The effects of solution composition, plasma gas composition, and stand-off distance on the composition of the deposited Ni-YSZ coatings by SPPS were evaluated. It was found that the addition of citric acid to the aqueous solution delayed re-solidification of NiO particles, improving the deposition efficiency and coating adhesion. The composition of the deposited coatings was found to vary with torch power. Increasing torch power led to coatings with decreasing Ni content, as a result of Ni vaporizing in-flight at stand-off distances less than 60 mm from the torch nozzle exit. (C) 2013 Elsevier By. All rights reserved.