화학공학소재연구정보센터
Journal of Power Sources, Vol.261, 264-270, 2014
Three-dimensional aluminum foam/carbon nanotube scaffolds as long- and short-range electron pathways with improved sulfur loading for high energy density lithium sulfur batteries
Conductive carbon scaffolds are efficient and effective to build advanced carbon/sulfur composite cathodes for lithium sulfur (Li-S) batteries. However, the areal sulfur loading is commonly less than 4.0 mg cm(-2), which limits the energy density and practical application of Li-S cells. In this contribution, three-dimensional (3D) aluminum foam/carbon nanotube (CNT) scaffolds were applied as the current collectors to build long- and short-range electron pathways and provided enough space for high sulfur loading. The sulfur loading amount on the 3D current collectors ranged from 7.0 to 12.5 mg cm(-2). A high initial discharge capacity of 6.02 mAh cm(-2) (860 mAh g(-1)) was achieved on an electrode with an improved sulfur loading of 7.0 mg cm-2. Therefore, the combination of 3D long-range current collectors and short-range CNT conductive scaffold provides an efficient and effective route to make full use of sulfur with a very high sulfur loading amount in a Li-S cell. (c) 2014 Elsevier B.V. All rights reserved.