화학공학소재연구정보센터
Journal of the American Ceramic Society, Vol.97, No.8, 2409-2412, 2014
Bulk Iodoapatite Ceramic Densified by Spark Plasma Sintering with Exceptional Thermal Stability
Iodoapatite powder prepared by high-energy ball milling is densified by Spark Plasma Sintering to similar to 96% theoretical density. X-ray Diffraction and First-principle Calculation indicates the sintered phase is iodine-deficient apatite with chemical composition of Pb-9.85(VO4)(6)I-1.7 and iodine confinement over 8 wt%. Thermogravimetric analysis shows the bulk iodoapatite displays exceptionally stability without iodine release until 670 degrees C. The greatly improved iodine confinement can be attributed to the dense matrix upon rapid consolidation from highly activated powders by mechanical attrition.