Journal of the American Chemical Society, Vol.136, No.3, 1054-1061, 2014
WMe6 Tamed by Silica: Si-O-WMe5 as an Efficient, Well-Defined Species for Alkane Metathesis, Leading to the Observation of a Supported W-Methyl/Methylidyne Species
The synthesis and full characterization of a well-defined silica-supported :Si-O-W(Me)(5) species is reported. Under an inert atmosphere, it is a stable material at moderate temperature, whereas the homoleptic parent complex decomposes above -20 degrees C, demonstrating the stabilizing effect of immobilization of the molecular complex. Above 70 degrees C the grafted complex converts into the two methylidyne surface complexes [( SiO-)W( CH)Me-2] and [( SiO-)(2)W( CH)Me]. All of these silica-supported complexes are active precursors for propane metathesis reactions.