Journal of the American Chemical Society, Vol.136, No.6, 2272-2275, 2014
Intramolecular Dearomatizing [3+2] Annulation of alpha-Imino Carbenoids with Aryl Rings Furnishing 3,4-Fused Indole Skeletons
The rhodium-catalyzed dearomatizing [3 + 2] annulation reaction of 4-(3-arylpropyl)-1,2,3-triazoles is described. It provides a straightforward synthetic pathway from simple 5-aryl-1-alkynes leading to tricyclic 3,4-fused dihydroindoles via the corresponding 1,2,3-triazoles.