화학공학소재연구정보센터
Journal of Chemical Technology and Biotechnology, Vol.74, No.11, 1082-1088, 1999
Regeneration of a catalyst based on a SAPO-34 used in the transformation of methanol into olefins
The regeneration by coke combustion of a catalyst based on a SAPO-34 used in the transformation of methanol into olefins (ethene and propene) has been studied. It has been observed that coke combustion kinetics are strongly dependent on the nature of the coke (H/C ratio), which in turn is a consequence of the reaction conditions (especially of the water content in the feed) and of the ageing level of the coke prior to its combustion. A severe ageing treatment is needed in order for combustion kinetics to be reproducible. Combustion is delayed due to the fact that coke is not an inert material but is bound to the acid sites.