Excess Molar Volumes of (X1Ch3Ch2Co2(CH2)2Ch3+x2Ch3(CH2)5Oh+(1-X1-X2)(CH3(CH2)4Ch3 or C-C6H12)) at the Temperature 298.15-K

Franjo C; Lorenzana MT; Legido JL; Andrade MI; Jimenez E

Journal of Chemical Thermodynamics, Vol.26, No.10, 1025-1030, 1994

DOI10.1006/jcht.1994.1120 Export Citation

Excess Molar Volumes of (X1Ch3Ch2Co2(CH2)2Ch3+x2Ch3(CH2)5Oh+(1-X1-X2)(CH3(CH2)4Ch3 or C-C6H12)) at the Temperature 298.15-K

Franjo C, Lorenzana MT, Legido JL, Andrade MI, Jimenez E

Excess molar volumes at the temperature 298.15 K of [x1CH3CH2CO2(CH2)2CH3 + x2CH3(CH2)5OH + (1 - x1 - x2){CH3(CH2)4CH3 or c-C6H12}] and of the binary mixtures {x1CH3CH2CO2(CH2)2CH3 + (1 - x1)CH3(CH2)5OH}, {x2CH3(CH2),OH + (1 - x2CH3(CH2)4CH3}, and {x2CH3(CH2)5OH + (1 - x2)c-C6H12} were determined using a densimeter Anton-Paar DMA 60/602. All the experimental values were compared with the results obtained by empirical expressions for estimating ternary properties from binary results. Variable-degree polynomials have been fitted to the results.

Keywords:THERMODYNAMIC PROPERTIES;BINARY-MIXTURES;1-ALKANOL;HEXANE