화학공학소재연구정보센터
Materials Chemistry and Physics, Vol.144, No.3, 390-395, 2014
Size and temperature consideration in the liquid layer growth from nanovoids and the melting model construction
A new model for the solid melting point T-m(D) from nanovoids is proposed through considering the liquid layer growth behavior. This model, which does not have any adjustable parameter, introduces the classical thermodynamic treatment, i.e., the liquid nucleation and growth theory, for nanoparticle melting. With increased void diameter D, T-m(D) approaches to T-m0. Moreover, T-m(D) > T-m0 for a small void (T-m0 is the bulk melting point). In other words, the solid can be significantly superheated especially when D decreases, even if the difference of interface energy is larger than zero. This finding can be expected from the negatively curved surface of the void. The model predictions are consistent with the molecular dynamic (MD) simulation results for argon solids. Moreover, the growth of liquid layer from void surface relies on both size and temperature, which directly determine liquid layer thickness, and only when liquid layer thickness reaches to a critical value, can void become instable. (C) 2014 Elsevier B.V. All rights reserved.