Materials Science Forum, Vol.353-356, 357-360, 2001
Valence sand splittings of 15R SiC measured using wavelength modulated absorption spectroscopy
15R SiC has significant advantages over 4H and 6H SiC for certain device applications. We have measured the free exciton low temperature photoluminescence (LTPL) spectrum for E perpendicular to (c) over cap and the wavelength derivative of the absorption coefficient d alpha /d lambda, of 15R SiC for both polarizations E perpendicular to (c) over cap and E parallel to (c) over cap using modulation absorption spectroscopy. We use the E perpendicular to (c) over cap intrinsic 2 K photoluminescence spectrum to make assignments to features in the E perpendicular to (c) over cap absorption derivative spectrum. We obtain 7.15 +/-0.25 meV for the spin orbit splitting, in agreement with previous work, but with improved precision. The determination of the crystal field splitting is more challenging. We argue for a value of about SI meV. This value is in good agreement with recent calculations.