Materials Science Forum, Vol.369-3, 785-792, 2001
Investigation of a new methodology in high temperature oxidation application to commercial austenitic steels
Avesta Sheffield R&D has evaluated a scaling temperature for heat resistant steels from laboratory gravimetric measurements of cyclic exposures. In this paper, this old method is described. A new methodology, based on the results of isothermal and cyclic tests, is proposed and discussed, It includes isothermal and cyclic oxidation kinetics of different commercial austenitic steels. Oxidation of Avesta Sheffield 153MA, 253MA and 353MA and standard commercial heat resistant steels 309S, 310S and A800 have been investigated under isothermal and cyclic conditions, in air, in the temperature range 800-1200 degreesC. For all alloys, oxidation rates obey a parabolic law below a critical temperature, The activation energies have been calculated. Kinetics of the cyclic tests show that a critical mass change corresponding to a critical thickness of the oxide scale is responsible for the spallation start. This thickness depends on the composition of the alloys, and is very much increased by alloying minor elements like Ce.
Keywords:cerium;cyclic conditions;Fe-Cr-Ni alloys;high temperature oxidation;isothermal conditions;kinetics of oxidation;oxide scale;reactive element;REM;spallation;test method