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Journal of Chemical Thermodynamics, Vol.30, No.7, 919-927, 1998
Second virial coefficients of chloromethane and chloroethane from measurements of the excess enthalpy of (0.5N(2)+0.5CH(3)Cl)(g), and (0.5N(2)+C2H5Cl)(g). The excess enthalpy of (0.5CH(3)Cl+0.5C(2)H(5)Cl)(g)
A gas-mixing flow calorimeter has been used to measure the excess molar enthalpy HmE of (nitrogen + chloromethane)(g), (nitrogen + chloroethane)(g), and (chloromethane + chloroethane)(g) at standard atmospheric pressure over the temperature range 250 K to 390 K. The measurements are analysed using the corresponding states correlation of Tsonopoulos with the acentric factor omega as a disposable parameter. From the value of w that fitted the HE measurements, values of the second virial coefficient B and the isothermal Joule-Thomson coefficient phi = B - T(dB/dT) were calculated. The values of B for chloromethane are in good agreement with other work, but at low temperatures those for chloroethane are less negative than previous measurements. The excess enthalpy of (chloromethane + chloroethane) is fitted using the mean value of w for the pure components.