화학공학소재연구정보센터
Materials Science Forum, Vol.404-7, 691-696, 2002
Changes in stress and microstructure in sputter deposited copper films due to substrate surface effects
Thin (500 nm thick) and ultra thin (5 nm thick) Cu films were sputter deposited on as-received and sputter cleaned amorphous Si(3)N(4) substrates. Their stresses were determined by the X-ray diffraction sin(2)psi method. Due to the strong Cu {111} texture, stress measurement by diffraction was possible also for the ultra thin films. High tensile stresses (422 MPa) developed in these films upon island coalescence. The growth stress of the 500nm thick films indicates a correlation with the morphological changes from globular to columnar structures upon substrate sputter cleaning prior to film deposition.