Materials Science Forum, Vol.433-4, 233-236, 2002
High-resolution XRD investigations of the strain reduction in 3C-SiC thin films grown on Si(111) substrates
In this work the biaxial stress of 3C-SiC thin films epitaxially grown on Si(l 11) substrates has been investigated by using x-ray diffraction methods. The influence of the resulting strain on the electrical properties of SiC/Si heterojunctions was analyzed. Different methods to prepare the surface prior to the SiC deposition were compared: (i) ex situ carbonization, (ii) interface modification by deposition of Ge prior to epitaxial growth and (iii) annealing of the silicon surface. The x-ray measurements revealed the lowest strain in ex situ carbonized samples, showing a transition from tensile to compressive strain when off-axis substrates were used. The highest strain appeared in SiC layers grown on a thin Ge intermediate layer which was deposited prior to SiC growth without an additional annealing step of the substrate. The strain in the SiC layer is directly correlated with the reverse current through the heterojunction.