화학공학소재연구정보센터
Materials Science Forum, Vol.461-464, 231-238, 2004
Investigation of oxide formation during short-term oxidation of model NiAl alloys
Two beta-NiAl model materials, one stoichiometric (50 at% Al) and one with low Al (39 at%) content were oxidized at 1050 degreesC for I h. FEB cross sections were analyzed by SEM and TEM. Phase identification was also performed by XRD. Strong influence of metal grain orientation on the diffusion and oxidation was observed. The morphology of the scale surface was similar in both materials and consisted of regions with needle-like oxide and small smoother pits. TEM and SEM analyses showed that the pits correspond to the contact areas between the oxide and the underlying alloy. Moreover TEM investigations revealed that these contact areas consist of alpha-Al2O3, while the detached oxide scale contains mainly transient-Al2O3 phases. The measured oxide thickness was similar in both contact and detached areas. The observed voids at the metal side were much more faceted in the Al-poor material. Possible mechanisms responsible for these observations are discussed.