Materials Science Forum, Vol.461-464, 1157-1164, 2004
High-temperature oxidation behaviour of base material and laser-weld specimens of a thin FeCrAl-RE foil at around 900 degrees C
Isothermal oxidation of laser welded FeCrAl-RE samples containing specific fractions of seams in a bead-on-plate "configuration" has been performed at around 900degreesC and studied using TGA, SEM, TEM and EPMA techniques. An important reduction in the alumina-growth rate on the fusion zone occurs at 900degreesC, thereby, suppressing the discontinuous increase in mass gain commonly observed during the high temperature oxidation of alumina-forming alloys. This phenomenon is mainly related to the concomitant dramatic chromium carbide precipitation at the fusion zone/scale interface and possible earlier injection of the rare earth elements into the scale. The former, which is linked to the laser melting-induced high free carbon, contributes to the increase in effectiveness of the diffusion barrier provided by the thermally growing scale. The latter is correlated with the initial high Ce+La enrichment at the fusion zone surfaces and is manifested by the elimination of detrimental platelet transformation during the initial stages of oxidation.
Keywords:laser welding;metastable alumina;alpha-Al2O3 nucleation;kinetics;transformation;interface;chromium carbides;grain growth;thickening of the platelets;reactivity anomaly