Conductance DLTS measurements have been performed on 4H-SiC MESFETs. A broad band due to electron emission by different levels is observed. An additional "hole-like" level with activation energy of 0.9 eV is obtained in linear regime but not in saturation regime. From the results, it is proposed that this "hole-like" signal is due to capture of electron present at a conductive SiC/SiO2 interfacial layer.