Characteristics of Film Preparation with Conducting Polyphenylenediamine Powder

Soo-Gil Park; Jae-Jin Na; Ju-Seong Lee; Robert A. Osteryoung

Journal of Industrial and Engineering Chemistry, Vol.2, No.2, 181-188, November, 1996

Soo-Gil Park, Jae-Jin Na, Ju-Seong Lee¹, and Robert A. Osteryoung²

Dept. of Ind. Chem. Eng., Chungbuk Nat'l Univ., Chungbuk 361-763, Korea
¹Dept. of Ind. Chem. Eng., Hanyang Univ., Seoul 133-791, Korea
²Dept. of Chemistry North Carolina Sate Unviersity, Raleign, NC 27695, Korea

Polyphenylenediamine (PPD) films were prepared by mixing the synthesized PPD powder and polyvinylacetate (PVA) as binder and then dissolving in dimethylsulfoxide (DMSO), m-cresol, N-methyl-2-pyrrolidione (NMP) as solvents. The chemical structure and properties of synthesized PPD were cofirmed with SEM, FT-lR, NMR, TGA. And the electrical conductivity was measured to confirm the electrical characteristics of PPD films. The electrical conductivity of film increased and showed the highest value when doped with 0.4% LiClO₄ solution. The film which had excellent high conductivity was prepared with DMSO in a mixture of PPD powder and PVA(1:1). And a good thermal stability (>350℃ ) of film was shown subject to doping in 0.4% HCI solution.

[References]

MacDiarmid AG, Epstein AJ, Synth. Met., 65, 103 (1994)
Genies EM, Picart S, Synth. Met., 69, 165 (1995)
Kanamura K, Tomura H, Shiraishi S, Takehara ZI, J. Electrochem. Soc., 142(2), 340 (1995)
The Technic and Application of Conductive Polymer, 319 (1988)
Katagiri N, Fujii T, Progress in Battreies & Battery Materials, 14 (1995)
Kabata T, Fujii T, Kimura O, Samura T, Matsuda Y, Watanable M, Polym. Adv. Technol., 4, 205 (1993)
Tatsuma T, Sotomura T, Sato T, Buttry DA, Oyama N, J. Electrochem. Soc., 142(10), L182 (1995)
MacDiarmid AG, Epstein AJ, Faraday Discuss. Chem. Soc., 88 (1989)
MacDiarmid AG, Epstein AJ, Faraday Discuss. Chem. Soc., 317 (1989)
Chiang JC, MacDiarmid AG, Synth. Met., 13 (1986)
MacDiarmid AG, Chiang JC, Richter AF, Somasiri NLD, Epstein AJ, Alcacer L, Conducting Polym. (1987)
Willstater R, Dorogi S, Chem. Ber., 42, 2143 (1909)
Mohillner DM, Adams RN, Argensinger WJ, J. Am. Chem. Soc., 184, 3618 (1962)
Wudl F, Angus RO, Lu FL, Allemand PM, Vachon DJ, Nowak M, Lui Z, Heeger A, J. Am. Chem. Soc., 109, 3677 (1986)
Wolf JF, Forbes CE, Gould S, Shacklette LW, J. Electrochem. Soc., 136(10) (1989)
Avlyanov JK, Min YG, MacDiarmid AG, Epstein AJ, Synth. Met., 72(1), 65 (1995)
Ye SY, Belanger D, J. Electrochem. Soc., 141(4), L49 (1994)
Genies EM, Picart S, Synth. Met., 69, 165 (1995)
Liu M, Visco SJ, DeJonghe LC, J. Electrochem. Soc., 138, 1891 (1991)
Baril D, Gautier M, Lasia A, Electrochim. Acta, 89, 709 (1994)
Chiodelli G, Scagliotti M, Solid State Ion., 73, 963 (1992)

[Referenced By]

[1] MacDiarmid AG, Epstein AJ, Synth. Met., 65, 103 (1994)

[2] Genies EM, Picart S, Synth. Met., 69, 165 (1995)

[3] Kanamura K, Tomura H, Shiraishi S, Takehara ZI, J. Electrochem. Soc., 142(2), 340 (1995)

[4] The Technic and Application of Conductive Polymer, 319 (1988)

[5] Katagiri N, Fujii T, Progress in Battreies & Battery Materials, 14 (1995)

[6] Kabata T, Fujii T, Kimura O, Samura T, Matsuda Y, Watanable M, Polym. Adv. Technol., 4, 205 (1993)

[7] Tatsuma T, Sotomura T, Sato T, Buttry DA, Oyama N, J. Electrochem. Soc., 142(10), L182 (1995)

[8] MacDiarmid AG, Epstein AJ, Faraday Discuss. Chem. Soc., 88 (1989)

[9] MacDiarmid AG, Epstein AJ, Faraday Discuss. Chem. Soc., 317 (1989)

[10] Chiang JC, MacDiarmid AG, Synth. Met., 13 (1986)

[11] MacDiarmid AG, Chiang JC, Richter AF, Somasiri NLD, Epstein AJ, Alcacer L, Conducting Polym. (1987)

[12] Willstater R, Dorogi S, Chem. Ber., 42, 2143 (1909)

[13] Mohillner DM, Adams RN, Argensinger WJ, J. Am. Chem. Soc., 184, 3618 (1962)

[14] Wudl F, Angus RO, Lu FL, Allemand PM, Vachon DJ, Nowak M, Lui Z, Heeger A, J. Am. Chem. Soc., 109, 3677 (1986)

[15] Wolf JF, Forbes CE, Gould S, Shacklette LW, J. Electrochem. Soc., 136(10) (1989)

[16] Avlyanov JK, Min YG, MacDiarmid AG, Epstein AJ, Synth. Met., 72(1), 65 (1995)

[17] Ye SY, Belanger D, J. Electrochem. Soc., 141(4), L49 (1994)

[18] Genies EM, Picart S, Synth. Met., 69, 165 (1995)

[19] Liu M, Visco SJ, DeJonghe LC, J. Electrochem. Soc., 138, 1891 (1991)

[20] Baril D, Gautier M, Lasia A, Electrochim. Acta, 89, 709 (1994)

[21] Chiodelli G, Scagliotti M, Solid State Ion., 73, 963 (1992)