화학공학소재연구정보센터
Polymer, Vol.55, No.5, 1103-1107, 2014
In-situ MR imaging on the plastic deformation of iPP thin films
The plastic deformation behavior of isotactic polypropylene (iPP) film is studied with in-situ Fourier transformation infrared microspectroscopic imaging (FTIRI). During uniaxial tensile test, spatial distributions of crystallinity and orientations are obtained in necking region (NR), transition front (TF) and non-necking region (NNR). A low valley of crystallinity exists at TF, while both NNR and NR have crystallinities at a high plateau. This provides a direct evidence of deformation-induced melting recrystallization mechanism of plastic deformation. The non-monotonic evolution of amorphous orientation from NR, IF to NNR further supports the occurrence of deformation-induced melting recrystallization. The decrease of amorphous orientation behind TF is attributed to recrystallization. (C) 2014 Published by Elsevier Ltd.