화학공학소재연구정보센터
Propellants Explosives Pyrotechnics, Vol.39, No.4, 504-510, 2014
Ammonium Perchlorate, Friend or Foe? Part 1: The Influence of this Oxidizer on the Aging Behavior of Propellant Compositions
Propellants containing nitroglycerine and ammonium perchlorate have been reported to have comparatively shorter shelf lives than analogous energetic materials without this oxidizer. However, investigation into the aging behavior of three compositions containing polyethylene glycol and nitroglycerine revealed that the propellant which included ammonium perchlorate degraded at a slower rate compared with the other materials. It was suggested that ammonium perchlorate might act as an oxygen inhibitor reducing the oxidation rate of the polyethylene glycol binder so decreasing the rate of the propellant decomposition. In addition, at temperatures of 80 degrees C or lower, ammonium perchlorate initially appears to hinder acid hydrolysis of nitroglycerine which also slows down the degradation of polyethylene glycol based propellant.