This paper presents a steady-state and transient theoretical exergy analysis of a. solar still, focused on the exergy destruction in the components of the still: collector plate, brine and glass cover. The analytical approach states an energy balance for each component resulting in three coupled equations where three parameters-solar irradiance, ambient temperature and insulation thickness-are studied. The energy balances are solved to find temperatures of each component; these temperatures are used to compute energy and exergy flows. Results in the steady-state regime show that the irreversibilities produced in the collector account for the largest exergy destruction, up to 615W/m(2) for a 935W/m(2) solar exergy input, whereas irreversibility rates in the brine and in the glass cover can be neglected. For the same exergy input a collector, brine and solar still exergy efficiency of 12.9%, 6% and 5% are obtained, respectively. The most influential parameter is solar irradiance. During the transient regime, irreversibility rates and still temperatures find a maximum 6 h after dawn when solar irradiance has a maximum value. However, maximum exergy brine efficiency, close to 93%, is found once T-col < T-w (dusk) and the heat capacity of the brine plays an important role in the modeling of collector-brine interaction. Nocturnal distillation is characterized by very low irreversibility rates due to reduced temperature difference between collector and an increase in exergy efficiency towards dawn due to ambient temperature decrease. (C) 2007 Elsevier Ltd. All rights reserved.