Ion imprinted activated carbon solid-phase extraction coupled to flame atomic absorption spectrometry for selective determination of lead ions in environmental samples

Kiyana Naraghi; Homayon Ahmad Panahi; Amir Hesam Hassani; Elham Moniri

Korean Journal of Chemical Engineering, Vol.31, No.10, 1818-1823, October, 2014

DOI10.1007/s11814-014-0104-5 Export Citation

Ion imprinted activated carbon solid-phase extraction coupled to flame atomic absorption spectrometry for selective determination of lead ions in environmental samples

Kiyana Naraghi, Homayon Ahmad Panahi^{1, †}, Amir Hesam Hassani, and Elham Moniri²

Department of Environmental Engineering, Faculty of Environmental and Energy, Science Research Branch, Islamic Azad University, Tehran, Iran
¹Department of Chemistry, Central Tehran Branch, Islamic Azad University, Tehran, Iran
²Department of Chemistry, Varamin (Pishva) Branch, Islamic Azad University, Varamin, Iran

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A simple lead ion imprinted sorbent was synthesized by coupling activated carbon with a known metal chelating compound, iminodiacetic acid. The ion imprinted sorbent has been characterized using Fourier transform infrared spectroscopy, elemental analysis and thermogravimetric analysis and subjected for the extraction and determination of trace Pb(II) in environmental water samples. The optimum pH value for sorption of the lead ion was 6.5. The sorption capacity of lead imprinted sorbent was 42.2 mg g^(-1). The chelating imprinted sorbent can be reused for five cycles of sorption-desorption without any significant change in sorption capacity. Compared with non-imprinted polymer particles, the lead ion imprinted sorbent showed high adsorption capacity, significant selectivity, good site accessibility for Pb(II). The equilibrium adsorption data of Pb(II) by modified resin were analyzed by Langmuir, Freundlich, Temkin and Redlich-Peterson models.

Keywords:Solid Phase Extraction;Polymer Grafting;Lead (II);Preconcentration;Isotherm Study

[References]

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ALOthman ZA, Yilmaz E, Habila M, Shabaka A, Soylak, Mikrochim. Acta, 180, 669 (2013)
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Li XA, Zhou DM, Xu JJ, Chen HY, Talanta, 71, 1130 (2007)
Tuzen M, Sesli E, Soylak M, Food Control, 18, 806 (2007)
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Kaqava S, Malek ZA, Araki Y, Haseqawa K, Anal. Sci., 18, 923 (2002)
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Elci L, Sahan D, Basaran A, Soylak M, Environ. Monit. Assess., 132, 331 (2007)
Chang X, Yang X, Wei X, Wu K, Anal. Chim. Acta, 450, 231 (2001)
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Tewari PK, Singh AK, Talanta, 56, 735 (2002)
Han DM, Fang GZ, Yan XP, J. Chromatogr. A, 1100, 131 (2005)
Jiang X, Zhao C, Jiang N, Zhang H, Liu M, Food Chem., 108, 1061 (2008)
Ahmad Panahi H, Morshedian J, Mehmandost N, Moniri E, Galaev IY, J. Chromatogr. A, 1217, 5165 (2010)
Panahi HA, Mottaghinejad E, Badr AR, Moniri E, J. Appl. Polym. Sci., 121(2), 1127 (2011)
Kumar M, Rathore DPS, Singh AK, Talanta, 51, 1187 (2000)
Xie F, Lin X, Wu X, Xie Z, Talanta, 74, 836 (2008)
Vinicius L, Gurgel A, Pereira de Freitas R, Frederic Gil L, Carbohydr. Polym., 74, 922 (2008)
Chen D, Hu B, Huang C, Talanta, 78, 491 (2009)
Filiz Senkal B, Ince M, Yavuz E, Yaman M, Talanta, 72, 962 (2007)
Melek E, Tuzen M, Soylak M, Anal. Chim. Acta, 578, 213 (2006)
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[Referenced By]

[1] Shah F, Soylak M, Kazi TG, Afridi HI, J. Anal. At. Spectrom., 8, 601 (2013)

[2] ALOthman ZA, Yilmaz E, Habila M, Shabaka A, Soylak, Mikrochim. Acta, 180, 669 (2013)

[3] Candir S,Narin I, Soylak M, Talanta, 77, 289 (2008)

[4] Lee Y, Oa SW, Environ. Eng. Res., 17, 145 (2012)

[5] Li XA, Zhou DM, Xu JJ, Chen HY, Talanta, 71, 1130 (2007)

[6] Tuzen M, Sesli E, Soylak M, Food Control, 18, 806 (2007)

[7] Yanovska ES, Tertykh VA, Kichkiruk OY, Dadashev AD, Adsorpt. Sci. Technol., 25, 81 (2007)

[8] Ghiasvand AR, Ghaderi R, Kakanejadifard A, Talanta, 62, 287 (2004)

[9] Kiriyoma T, Kuroda R, Fresenius J. Anal. Chem., 332, 338 (1988)

[10] Kubova J, Neveral V, Stresko V, J. Anal. At. Spectrom., 9, 241 (1994)

[11] Malvankar PL, Shinde VM, Analyst, 116, 1081 (1991)

[12] Soylak M, Elci L, Int. J. Environ. Anal. Chem., 66, 51 (1997)

[13] Santelli RE, Gallego M, Valcarcel M, Anal. Chem., 61, 1427 (1989)

[14] Elci L, Saracoqglu S, Talanta, 46, 1305 (1998)

[15] Kagaya S, Araki Y, Hasegawa K, Fresenius J. Anal. Chem., 366, 842 (2000)

[16] Kaqava S, Malek ZA, Araki Y, Haseqawa K, Anal. Sci., 18, 923 (2002)

[17] Ahmad Panahi H, Morshedian J, Mehmandost N, Moniri E, Galaev IY, J. Chromatogr. A, 1217, 5165 (2010)

[18] Elci L, Arslan Z, Tyson JF, Spectrochim. Acta Part B, 55, 1109 (2000)

[19] Soliman EM, Mahmoud ME, Ahmed SA, Talanta, 54, 243 (2001)

[20] Elci L, Sahan D, Basaran A, Soylak M, Environ. Monit. Assess., 132, 331 (2007)

[21] Chang X, Yang X, Wei X, Wu K, Anal. Chim. Acta, 450, 231 (2001)

[22] Chang X, Su Q, Liang D, Wei X, Wang B, Talanta, 57, 253 (2002)

[23] Bezerra MA, dos Santos WNL, Lemos VA, Korn MDGA, Ferreira SLC, J. Hazard. Mater., 148(1-2), 334 (2007)

[24] Pyrzynska K, Crit. Rev. Anal. Chem., 29, 313 (1999)

[25] Ahmed SA, J. Hazard. Mater., 156(1-3), 521 (2008)

[26] Tewari PK, Singh AK, Talanta, 56, 735 (2002)

[27] Han DM, Fang GZ, Yan XP, J. Chromatogr. A, 1100, 131 (2005)

[28] Jiang X, Zhao C, Jiang N, Zhang H, Liu M, Food Chem., 108, 1061 (2008)

[29] Ahmad Panahi H, Morshedian J, Mehmandost N, Moniri E, Galaev IY, J. Chromatogr. A, 1217, 5165 (2010)

[30] Panahi HA, Mottaghinejad E, Badr AR, Moniri E, J. Appl. Polym. Sci., 121(2), 1127 (2011)

[31] Kumar M, Rathore DPS, Singh AK, Talanta, 51, 1187 (2000)

[32] Xie F, Lin X, Wu X, Xie Z, Talanta, 74, 836 (2008)

[33] Vinicius L, Gurgel A, Pereira de Freitas R, Frederic Gil L, Carbohydr. Polym., 74, 922 (2008)

[34] Chen D, Hu B, Huang C, Talanta, 78, 491 (2009)

[35] Filiz Senkal B, Ince M, Yavuz E, Yaman M, Talanta, 72, 962 (2007)

[36] Melek E, Tuzen M, Soylak M, Anal. Chim. Acta, 578, 213 (2006)

[37] Tewari PK, Singh AK, Talanta, 56, 735 (2002)