Laser-induced Polyacrylamide/PVA Film with Large Diffraction Index

Hooi Sung Kim; Chon Su Kyong; Gee Young Sung; Chong Hoon Kwak; Jin Kook Lee

Journal of Industrial and Engineering Chemistry, Vol.5, No.1, 65-68, March, 1999

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Laser-induced Polyacrylamide/PVA Film with Large Diffraction Index

Hooi Sung Kim, Chon Su Kyong¹, Gee Young Sung¹, Chong Hoon Kwak¹, and Jin Kook Lee^†

Department of Polymer Science & Engineering, Pusan National University, Pusan 609-735, Korea
¹Department of Physics, Yeungnam University, Kyongsan 712-749, Korea

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Polyacrylamide film was fabricated using polyvinylalcohol as a binder with He-Ne laser(633 nm). The methylene blue/triethanolamine system was used. The formation kinetics was proved by Ar-ion laser (488 nm). Diffraction efficiency for different amounts of acrylamide was measured and an optimizing amount of monomer (6%) was determined. The photobleaching rate constant by Beer-Lambert equation was also determined. Photochemical bleaching and diffraction properties of photo-polymer was explained. The holographic grating with 1000 lines/mm and maximum diffraction efficiency (80%) were obtained.

Keywords:photopolymer;methylene blue;triethanolamine;hologram;diffraction efficiency

[References]

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[Referenced By]

[1] Calixto S, Appl. Opt., 26, 3904 (1987)

[2] Smothers WK, Monroe BM, Weber AM, Keys DE, SPIE, 1212, 20 (1990)

[3] Simmons EL, J. Phys. Chem., 75, 588 (1971)

[4] Beeson KW, Horn KA, Lau C, SPIE, 1559, 258 (1991)

[5] Leclere P, Manivannan G, Changkakoti R, SPIE, 2042, 35 (1994)

[6] Martin S, Fourth International Conference on Holographic Systems, Components and Applications, September, 71, 13 (1993)

[7] Jenney JA, J. Opt. Soc. Am., 60, 1155 (1970)

[8] Oster G, Nature, 173, 300 (1954)

[9] Eaton DF, Advances in Photochemistry, Vol. 13, Chap. 4, John Wiley & Sons, New York (1986)

[10] Kustermann E, Timple HJ, Gabert K, Schulert H, Wiss. Z. Tech. Hochsch. Merseburg, 29, 287 (1987)

[11] Chen CJ, J. Polym. Sci. A: Polym. Chem., 3, 1107 (1965)

[12] Chen CJ, J. Polym. Sci. A: Polym. Chem., 3, 1127 (1965)

[13] Chen CJ, J. Polym. Sci. A: Polym. Chem., 3, 1137 (1965)

[14] Chen CJ, J. Polym. Sci. A: Polym. Chem., 3, 1155 (1965)

[15] Vedeneev AA, Khudyakov IV, Golubkova NA, Kuzmin VA, Irinyi GJ, J. Chem. Soc.-Faraday Trans., 86, 3545 (1990)

[16] Kayser RH, Young RH, Photochem. Photobiol., 24, 395 (1976)

[17] Kayser RH, Young RH, Photochem. Photobiol., 24, 403 (1976)

[18] Previtali CM, Bertolotti SG, Neumann MG, Pastre IA, Rufs AM, Encinas MV, Macromolecules, 27(25), 7454 (1994)

[19] Neumann MG, Rodrigues MR, Polymer, 39(8-9), 1657 (1998)

[20] Capolla N, Lessard RA, Appl. Opt., 27, 3008 (1988)