Characterization of V2O5-ZrO2-WO3 and Activity for Propylene Partial Oxidation

Im Ja Doh; Young Il pae; Jong Rack Sohn

Journal of Industrial and Engineering Chemistry, Vol.5, No.3, 161-169, September, 1999

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Characterization of V₂O₅-ZrO₂-WO₃ and Activity for Propylene Partial Oxidation

Im Ja Doh, Young Il pae, and Jong Rack Sohn^{1, †}

Department of Chemistry, University of Ulsan, Ulsan 680-749, Korea
¹Department of Industrial Chemistry, Engineering College, Kyungpook National University, Taegu 702-701, Korea

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V₂O₅-ZrO₂ modified with WO₃ was prepared by adding the Zr(OH)₄ powder into a mixed aqueous solution of ammonium metavanadate and ammonium metatungstate followed by drying and calcining at high temperatures. The characterization of the prepared catalysts was performed using FTIR, solid-state ⁵¹V NMR, XRD, and DSC. In the case of calcination temperature at 773 K, for the samples containing low loading V₂O₅ below 18 wt % vanadium oxide was in a highly dispersed state, while for samples containing high loading V₂O₅ equal to or above 18 wt % vanadium oxide was well crystallized due to the V₂O₅ loading exceeding the formation of monolayer on the surface of catalyst. The ZrV₂O₇ compound was formed through the reaction of V₂O₅ and ZrO₂ at 873 K and decomposed into V₂O₅ and ZrO₂ at 1073 K, which were confirmed by FTIR, solid-state ⁵¹ NMR, and XRD. V₂O₅-ZrO₂-WO₃(15) series catalysts exhibited the effective catalytic activity for propylene partial oxidation and the activity increased with increasing V₂O₅ content reaching a maximum at 12 wt % V₂O₅.

Keywords:V₂O₅-ZrO₂-WO₃;characterization;FTIR;solid-state ⁵¹ NMR;XRD;propylene partial oxidation

[References]

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Elmi AS, Tronoconi E, Cristiani C, Martin JPG, Forzatti P, Ind. Eng. Chem. Res., 84, 237 (1989)
Miyata H, Fujii K, Ono T, Kubokawa Y, Ohno T, Hatayama F, J. Chem. Soc.-Faraday Trans., 83, 675 (1987)
Cavani F, Centi G, Foresti E, Trifiro F, J. Chem. Soc.-Faraday Trans., 84, 237 (1988)
Hayata F, Ohno T, Maruoka T, Miyata H, J. Chem. Soc.-Faraday Trans., 87, 2629 (1991)
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Larsen G, Lotero E, Petkovic LM, Shobe DS, J. Catal., 169(1), 67 (1997)
Afanasiev P, Geantet C,Breysse M, Coudurier G, Vedrine JC, J. Chem. Soc.-Faraday Trans., 90, 193 (1994)
Roozeboom F, Mittelmeljer-Hazeleger MC, Moulijin JA, Medema J, de Beer VHJ, Gellings PJ, J. Phys. Chem., 84, 7283 (1980)
Livage J, Doi K, Mazieres C, J. Am. Ceram. Soc., 51, 349 (1968)
Sohn JR, Pae YI, Park MY, Jo SG, React. Kinet. Catal. Lett., 55, 325 (1995)
Busca G, Machetti L, Centi G, Trifiro F, J. Chem. Soc.-Faraday Trans., 91, 1003 (1985)
Ai M, Suzuki S, Bull. Chem. Soc. Jpn., 47, 3074 (1974)
Sohn JR, Cho HS, Kim HW, J. Ind. Eng. Chem., 5(1), 1 (1999)
Sohn JR, Park MY, Langmuir, 14(21), 6140 (1998)

[Referenced By]

[1] Nakagawa Y, Ono T, Miyata H, Kubokawa Y, J. Chem. Soc.-Faraday Trans., 79, 2929 (1983)

[2] Miyata H, Kohno M, Ono T, Ohno T, Hatayama F, J. Chem. Soc.-Faraday Trans., 85, 3663 (1989)

[3] Mars P, van Krevelen DW, Spec. Suppl. Chem. Eng., 3, 41 (1954)

[4] Sachtler WMH, Catal. Rev., 4, 27 (1970)

[5] Forzatti P, Tronoconi E, Busca G, Titarellp P, Catal. Today, 1, 209 (1987)

[6] Busca G, Elmi AS, Forzatti P, J. Phys. Chem., 91, 5263 (1987)

[7] Elmi AS, Tronoconi E, Cristiani C, Martin JPG, Forzatti P, Ind. Eng. Chem. Res., 84, 237 (1989)

[8] Miyata H, Fujii K, Ono T, Kubokawa Y, Ohno T, Hatayama F, J. Chem. Soc.-Faraday Trans., 83, 675 (1987)

[9] Cavani F, Centi G, Foresti E, Trifiro F, J. Chem. Soc.-Faraday Trans., 84, 237 (1988)

[10] Hayata F, Ohno T, Maruoka T, Miyata H, J. Chem. Soc.-Faraday Trans., 87, 2629 (1991)

[11] Arco M, Holgado MJ, Martin C, Rives V, Langmuir, 6, 801 (1990)

[12] Centi G, Pinelli D, Trifiro F, Ghoussoub D, Guelton M, Gengembre L, J. Catal., 130, 238 (1991)

[13] Inomata M, Mori K, Miyamoto A, Murakami Y, J. Phys. Chem., 87, 761 (1983)

[14] Scharf U, Schraml Marth M, Wokaun A, Baiker A, J. Chem. Soc.-Faraday Trans., 87, 3299 (1991)

[15] Miyata H, Kohno M, Ono T, Ohno T, Hatayama F, J. Mol. Catal., 63, 181 (1990)

[16] Sohn JR, Park MY, Pae YI, Bull. Korean Chem. Soc., 17, 274 (1996)

[17] Hayashi S, Hayamizu K, Bull. Chem. Soc. Jpn., 63, 961 (1990)

[18] Mori K, Miyamoto A, Murakami Y, J. Chem. Soc.-Faraday Trans., 83, 3303 (1987)

[19] Bjorklund RB, Odenbrand CUI, Brandin JGM, Anderson LAH, Liedberg B, J. Catal., 119, 187 (1989)

[20] Sohn JR, Cho SG, Pae YI, Hayashi S, J. Catal., 159(1), 170 (1996)

[21] Roozeboom F, Mittelmelijer-Hazeleger MC, Moulijn JA, Medema J, de Beer UHJ, Gelling PJ, J. Phys. Chem., 84, 2783 (1980)

[22] Eckert H, Wachs IE, J. Phys. Chem., 93, 6796 (1989)

[23] Reddy BM, Reddy EP, Srinivas ST, Mastikhim VM, Nosov NV, Lapina OB, J. Phys. Chem., 96, 7076 (1992)

[24] Le Costumer LR, Taouk B, Le Meur M, Payen E, Guelton M, Grimblot J, J. Phys. Chem., 92, 1230 (1988)

[25] Narsimha K, Reddy BM, Rao PK, Mastikhin VM, J. Phys. Chem., 94, 7336 (1990)

[26] Sobalik Z, Lapina OB, Novgorodova ON, Mastikhin VM, Appl. Catal., 63, 191 (1990)

[27] Larsen G, Lotero E, Petkovic LM, Shobe DS, J. Catal., 169(1), 67 (1997)

[28] Afanasiev P, Geantet C,Breysse M, Coudurier G, Vedrine JC, J. Chem. Soc.-Faraday Trans., 90, 193 (1994)

[29] Roozeboom F, Mittelmeljer-Hazeleger MC, Moulijin JA, Medema J, de Beer VHJ, Gellings PJ, J. Phys. Chem., 84, 7283 (1980)

[30] Livage J, Doi K, Mazieres C, J. Am. Ceram. Soc., 51, 349 (1968)

[31] Sohn JR, Pae YI, Park MY, Jo SG, React. Kinet. Catal. Lett., 55, 325 (1995)

[32] Busca G, Machetti L, Centi G, Trifiro F, J. Chem. Soc.-Faraday Trans., 91, 1003 (1985)

[33] Ai M, Suzuki S, Bull. Chem. Soc. Jpn., 47, 3074 (1974)

[34] Sohn JR, Cho HS, Kim HW, J. Ind. Eng. Chem., 5(1), 1 (1999)

[35] Sohn JR, Park MY, Langmuir, 14(21), 6140 (1998)