Sulfonic acid functionalized poly (ethylene glycol dimethacrylate-1-vinyl-1,2,4-triazole), poly (EGDMA-VTAZ-SO(3)H) (average diameter 1.0-1.5 mm), was found to be efficient solid acid catalyst for the esterification of methanol and propionic acid under heterogeneous reaction conditions. The pristine polymer, poly (EGDMA-VTAZ), was produced by suspension polymerization and then proton-conducting polymer was obtained by blending of poly (EGDMA-VTAZ) with different percentage of H(2)SO(4) solutions. The protonation of aromatic heterocyclic rings was proved with Fourier-transform infrared spectroscopy (FT-IR). Thermo gravimetric (TG) analysis showed that the catalyst is thermally stable up to 573 K. The surface morphology of the catalyst was characterized by scanning electron microscopy (SEM). Poly (EGDMA-VTAZ-SO(3)H) beads can be regenerated and reused, so this provides a potential application. It has a rate constant which exceeds that of Amberlyst-15 by a factor of about four at 333 K. As for the reaction equilibrium constant (K(e)), which is independent of temperature ranging from 318 to 343 K, was determined to be 3.16. The apparent activation energy was found to be 41.6 kJ mol(-1) for poly (EGDMA-VTAZ-SO(3)H). (C) 2010 Elsevier Ltd. All rights reserved.