A comprehensive study of the surface properties of the gamma-AL(2)O(3) in KNO3 as a function of temperature was undertaken potentiometrically. Surface charge, ionization and complexation constants, and PZC were calculated from the potentiometric titration data in the temperature range 293-333 K. A difference between the PZC and CIP was observed as a result of the adsorption of NO3- ions. A simple graphical procedure based on the mass action law was used to determine the number of surface sites and equilibrium constants. Thermodynamic parameters, which showed a decrease in the role of nitrate NO3- ion in the charging mechanism of gamma-Al2O3, were also evaluated, whereas that of K+ ion increased with the increase in temperature.