A first representative of a new group of proton conducting materials, imidazolium selenate dihydrate: (IMD)(2)SeO4 center dot 2H(2)O, was successfully synthesized. The structural and thermal properties, proton conductivity, and the dynamics of the salt obtained were studied by different analytical methods including X-ray diffraction (XRD), differential scanning calorimetry (DSC), impedance spectroscopy, Fourier transform infrared spectroscopy (FUR), and magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy. The structural studies showed that the selenate anions and imidazolium cations bridged by crystalline water molecules formed a network of hydrogen bonds. This network is essential for proton conduction. The highest value of proton conductivity in (IMD)(2)SeO4 center dot 2H(2)O was found to be approximately 10(-1) S/m at 333 K. The C-13 MAS NMR spectrum indicates that the imidazolium rings undergo fast reorientations and contribute to the effective proton conduction process. (C) 2012 Elsevier B.V. All rights reserved.