A computational approach is implemented to characterize multicomponent charged-defect transport and apparent gas-phase permeation associated with proton-conducting perovskite membranes across a very wide range of gas-phase environments. The Nernst-Planck-Poisson (NPP) model predicts charged-defect and electrostatic-potential profiles within the membrane as well as apparent gas-phase fluxes entering and leaving the membrane surfaces. Results are represented as two-dimensional contour maps, enabling the large amounts of information to be presented in a compact graphical format. The results provide qualitative and quantitative insights about membrane permeation phenomena as functions of gas-phase environments across the membrane. Although the study considers the properties of a particular yttria-doped barium zirconate (BZY20), the modeling approach and qualitative insights are more widely applicable to classes of similar materials. (C) 2013 Elsevier B.V. All rights reserved.