Solar Energy Materials and Solar Cells, Vol.108, 44-49, 2013
Experimental study on the elimination of over-plating problems in industrial manufacturing of large-area acidic-textured laser-doped multi-crystalline solar cells
Light-induced plating (LIP) techniques, which are self-aligned and are used in the fabrication of well-shaped metal grids, have been widely studied and used in solar cells, particularly in laser-doped selective emitter (LDSE) ones. However, the application of LIP techniques in standard acidic-textured multi-crystalline silicon wafers with SiNx-coated surfaces can be challenging because of the presence of some unwanted metals on the SiNx surface during the plating process. This phenomenon is called over-plating, a problem in industrial LDSE multi-crystalline Si solar cell manufacturing that this paper aims to eliminate without the addition of any new process steps. The feasibility of changing the texturing process as well as the pretreatment before plating and the deposition of SiNx to reduce over-plating was investigated. The effects of over-plating on solar cell performance were also investigated to determine the mechanism of performance degradation. The cells reached a maximum efficiency of 17.2% and an average efficiency of 171% on large-area, commercial-grade, p-type multi-crystalline Si substrates when the over-plating problem was eliminated. Crown Copyright (C) 2012 Published by Elsevier B.V. All rights reserved.
Keywords:Light-induced plating;Over-plating;Acidic texturing;Laser-doped selective emitter solar cells;Multi-crystalline Si