Open-cell nickel foams with 92% porosity and uniform pore size and distribution were used in this study. The main objective of this work was to evaluate the behaviour of Ni-foam, when treated as volumetric receivers under concentrated solar radiation while improving their oxidation resistance, in order to make them attractive for such applications. The experimental investigation showed that their efficiency was depending on both materials parameters and flow conditions, the latter affecting the pressure drop and the heat transfer behaviour. The microstructural characterisation of oxide surface morphologies formed on the open-cell Ni foams exposed to concentrated solar radiation is investigated by the use of SEM and EDXS. SEM observations revealed a rapid homogeneous oxidation in the Ni-foam with three different surface oxide structures formed in relation with the process temperature. A novel slurry-based process for aluminising nickel foams while retaining their geometrical properties is applied in order to develop an aluminide-nickel intermetallic coating on a Ni foam thus enhancing the oxidation resistance. Scanning electron microscopy and X-ray diffraction were applied to assess the effectiveness of the aluminising process and determine the optimum parameters of the procedure (slurry composition, holding temperature and time). (C) 2012 Elsevier B.V. All rights reserved.