화학공학소재연구정보센터
Solar Energy Materials and Solar Cells, Vol.120, 506-511, 2014
Breakdown characteristics of flexible Cu(In,Ga)Se-2 solar cells
The behavior of solar cells under reverse bias conditions is of crucial importance for solar module design and stability. For flexible, low temperature deposited Cu(In,Ga)Se-2 (CIGSe) solar cells indications for tunnel breakdown at operation temperatures around 300 K are found using temperature and net carrier concentration dependent measurements of the breakdown voltage V-BR. For temperatures below 200 K, the temperature coefficient of the breakdown voltage becomes positive, indicating a change of the breakdown mechanism to avalanche breakdown. A reduction of V-BR caused by the illumination with blue photons is demonstrated, which coincides well with results and models for high temperature deposited CIGSe on glass. Furthermore, spectrally resolved measurements of light emission during breakdown indicate a first ReBEL (reverse bias electroluminescence) signature for CIGSe solar cells. (C) 2013 Elsevier B.V. All rights reserved.