화학공학소재연구정보센터
Solar Energy Materials and Solar Cells, Vol.122, 287-296, 2014
Solar thermophotovoltaic energy conversion systems with two-dimensional tantalum photonic crystal absorbers and emitters
Solar thermophotovoltaic (STPV) systems convert solar energy into electricity via thermally radiated photons at tailored wavelengths to increase energy conversion efficiency. In this work, we report the design and analysis of a STPV system with 2D photonic crystals (PhCs) using a high-fidelity thermal-electrical hybrid model that includes the thermal coupling between the absorber/emitter/PV cell and accounts for non-idealities such as temperature gradients and parasitic thermal losses. The desired radiative spectra of the absorber and emitter were achieved by utilizing an optimized two-dimensional periodic square array of cylindrical cavities on a tantalum (Ta) substrate. Various energy loss mechanisms including re-emission at the absorber, low energy emission at the emitter, and a decrease in the emittance due to the angular dependence of PhCs were investigated with varying irradiation flux onto the absorber and resulting operating temperature. The modeling results suggest that the absorber-to-electrical efficiency of a realistic planar STPV consisting of a 2D Ta PhC absorber/emitter and current state of the art InGaAsSb PV cell (whose efficiency is only similar to 50% of the thermodynamic limit) with a tandem filter can be as high as similar to 10% at an irradiation flux of similar to 130 kW/m(2) and emitter temperature similar to 1400 K. The absorber-to-electrical STPV efficiency can be improved up to similar to 16% by eliminating optical and electrical non-idealities in the PV cell. The high spectral performance of the optimized 2D Ta PhCs allows a compact system design and operation of STPVs at a significantly lower optical concentration level compared with previous STPVs using macro-scale metallic cavity receivers. This work demonstrates the importance of photon engineering for the development of high efficiency STPVs and offers a framework to improve the performance of both PhC absorbers/emitters and overall STPV systems. (C) 2013 Elsevier B.V. All rights reserved.