A mathematical model of a solar chimney was proposed in order to predict its performance under varying ambient and geometrical features. Steady state heat transfer equations were set up using a thermal resistance network and solved using matrix inversion. Existing correlations of heat transfer coefficients were utilised. Property values for the air flow in the duct were based on mean bulk or film temperatures. The performance of the chimney was evaluated by predicting the temperatures of the glass glazing and the heat-absorbing wall and also the temperature and velocity of the induced air flow in the chimney. The effects of air gap and solar radiation intensity on the performance of different chimneys were investigated. In order to verify the theoretical model, experiments were conducted on a 2 m high x 0.45 m wide physical model with air gaps of 0.1, 0.2 and 0.3 m. Experiments were carried out outdoors on the roof and the experimental model exposed to both direct and diffuse solar radiation. Air velocities between 0.25 m s(-1) and 0.39 m s(-1) for radiation intensity up to 650 Wm(-2) were obtained. No reverse air flow circulation was observed even at the large gap of 0.3 m. (C) 2003 Elsevier Science Ltd. All fights reserved.