In this paper, an attempt is made to estimate the internal heat transfer coefficients of a deep basin hybrid (PV/T) active solar still. The estimation is based on outdoor experimental observation of hybrid (PV/T) solar still for composite climate of New Delhi (latitude 28 degrees 35'N and longitude 77 degrees 12'E). The internal heat transfer coefficients are evaluated by using thermal models proposed by various researchers. The comparison of hourly yield predicted using various thermal models to the experimental has also been carried out by evaluating the correlation coefficient and percentage deviation. It is observed that, Kumar and Tiwari model (KTM) better validate the results than the others model. The average annual values of convective heat transfer coefficient for the passive and hybrid (PV/T) active solar still are observed as 0.78 and 2.41 W m(-2) K(-1), respectively at 0.05 in water depth. (C) 2009 Elsevier Ltd. All rights reserved.