A novel and affordable solar selective coating exhibiting higher solar absorption efficiency compared to the commercial black paint coating used in most ordinary solar water heating systems (SWHSs) has been developed. The coating is fabricated by embedding a metallic particle composed of a nickel-aluminium (NiAl) alloy into the black paint. The optical behaviour of several percentages of the NiAl alloy in the coating is studied using UV-Vis and IR spectroscopies. The chemical composition of the coating was characterized using XRD and thermo-gravimetric analysis (TGA) for both the black and alloy-containing paint. The results allowed deducing that the optimum composition to consider for further testing was 6% NiAl alloy by mass. The applicability of the coating in a real thermosyphonic SWHS was evaluated throughout the year, spanning both hot and cold seasons. It is found that the new coating shows better performance compared to the untreated black paint by an average of 5 degrees C over a period of 1 year. The corrosion resistance of the coating was investigated using electrochemical polarization and weight-loss measurements in the corrosive medium of 3% NaCl in 0.50 M HCl. Higher inhibition efficiency of corrosion was found for the alloy-containing paint compared to the untreated paint by more than 12%. Finally, Scanning Electron Microscopy (SEM) was used to explore the morphology of the modified coating surface, and compared to the untreated surface. (C) 2010 Elsevier Ltd. All rights reserved.