The influence of using pyridinium molten salts as co-adsorbents to modify the monolayer of a TiO(2) semiconductor on the performance of a dye-sensitized solar cell is studied. The current-voltage characteristics are measured under AM 1.5 (100 mW cm(-2)). The pyridinium molten salts significantly enhance the open-circuit photovoltage (V(oc)), the short circuit photocurrent density (J(sc)) as well as the solar energy conversion efficiency (eta). 1-Ethyl-3-carboxypyridinium iodide ([ECP][I]) is applied successfully to prepare an insulating molecular layer with N719, and achieve high energy conversion efficiency as high as 4.49% at 100 mW cm(-2) and AM 1.5. The resulting efficiency is 20% higher than that of a non-additive device. This enhancement of conversion efficiency is attributed to the negative shift of the conduction band (CB) edge and the abundant concentration of I(-) on the surface of the electrode when using [ECP][I] as the co-adsorbent. (C) 2010 Elsevier Ltd. All rights reserved.