Optimum conditions for testing N-nitrosamine formation potential (FP) through ozonation in wastewater samples

Suchul Yoon; Hiroaki Tanaka

Journal of Industrial and Engineering Chemistry, Vol.20, No.5, 2914-2920, September, 2014

DOI10.1016/j.jiec.2013.11.028 Export Citation

Optimum conditions for testing N-nitrosamine formation potential (FP) through ozonation in wastewater samples

Suchul Yoon^†, and Hiroaki Tanaka

Research Center for Environmental Quality Management, Kyoto University, 1-2 Yumihama, Otsu, Shiga 520-0811, Japan

E-mail:

N-nitrosamines are potential carcinogens that are formed during disinfection by chlorination/ chloramination or ozonation. In this study, the main objective was to optimize ozonation experimental conditions (pH and temperature) for the production of N-nitrosamines by using the CCD method in wastewater matrices. As the results, maximum NDMA FPO3 (formation potential by ozonation) occurred at pH 8.96 and a temperature of 20.0 ℃. Furthermore, attempts to reduce the concentrations of eight Nnitrosamines revealed that none was removed or reduced in concentration by ozonation using Milli-Q water for 2 h.

Keywords:N-nitrosamines;Formation potential (FP);Ozonation;Response surface methodology (RSM);Central composite design (CCD)

[References]

Shapley D, Science, 191, 268 (1976)
Mitch WA, Sedlak DL, Environ. Sci. Technol., 36, 588 (2002)
Mitch WA, Sedlak DL, Water Sci. Technol. Water Supply, 2, 191 (2002)
Krasner SW, Weinberg HS, Richardson SD, Pastor SJ, Chinn R, Sclimenti MJ, Onstad GD, Thruston AD, Environ. Sci. Technol., 40, 7175 (2006)
Choi JH, Valentine RL, Water Res., 36, 817 (2002)
Valentine RL, Brandt KI, Jafvert CT, Water Res., 20, 1067 (1986)
Water Reuse Foundation, Removal and Destruction of NDMA and NDMA Precursors during Wastewater Treatment (2005) Chapter 5, 10.
Lee C, Schmidt C, Yoon J, Von GU, Environ. Sci. Technol., 41, 2056 (2007)
Lee C, Schmidt C, Yoon J, Von GU, Water Res., 41, 581 (2007)
Andrzejewski P, Kasprzyk HB, Nawrocki J, Water Res., 42, 863 (2008)
Schmidt CK, Brauch HJ, Environ. Sci. Technol., 42, 6340 (2008)
Oya M, Kosaka K, Asami M, Kunikane S, Chemosphere, 73, 1724 (2008)
Oya M, Kosaka K, Asami M, Kunikane S, Proceedings of 42nd Annual Conference of Japan Society on Water Environment, 2008, p. 161 (in Japanese).
Oya M, Kosaka K, Asami M, Kunikane S, Proceedings of 18th Annual Conference on Ozone Science and Technology in Japan, 2008, p. 17 (in Japanese).
Hollender J, Zimmermann SG, Koepke S, Krauss M, McArdell CS, Ort C, Singer H, von GU, Siegrist H, Environ. Sci. Technol., 43, 7862 (2009)
Kosaka K, Asami M, Konno Y, Oya M, Kunikane S, Environ. Sci. Technol., 43, 5236 (2009)
Zhao YY, Boyd J, Hrudey SE, Li XF, Environ. Sci. Technol., 40, 7636 (2006)
Chen Z, Valentine RL, Environ. Sci. Technol., 40, 7290 (2003)
Myers RH, Montgomery DC, A Wiley-Interscience Publication, 2002.
Montgomery DC, Runger GC, Hubele NF, Engineering Statistics, John Wiley and Sons Inc., Hoboken, NJ, 2001.
Vining GG, Statistical Methods for Engineers, Duxburg Press/An International Thomason Publishing, Europe/London, 2003.
Parajo JC, Alonso JL, Lage MA, Vazquez D, Bioprocess Eng., 8, 129 (1992)
Muthukumar M, Sargunmani D, Selvakumar N, Venkata RJ, Dyes Pigment., 63, 127 (2004)
Beg Q, Sahai V, Gupta R, Process Biochem., 39, 203 (2003)
Mayerhoff Z, Robert I, Franco T, Biochem. Eng. J., 18, 217 (2004)
Wen ZY, Liao W, Chen SL, Bioresour. Technol., 96(4), 491 (2005)
Fouillet B, Odoul M, Chambon P, Chambon R, Castegnaro M, Bull. Environ. Contam. Toxicol., 52, 681 (1994)
Zulkali MMD, Ahmad AL, Norulakmal NH, Bioresour. Technol., 97(1), 21 (2006)
Ravikumar K, Krishnan S, Ramalingam S, Balu K, Dyes Pigment., 72, 66 (2007)

[1] Shapley D, Science, 191, 268 (1976)

[2] Mitch WA, Sedlak DL, Environ. Sci. Technol., 36, 588 (2002)

[3] Mitch WA, Sedlak DL, Water Sci. Technol. Water Supply, 2, 191 (2002)

[4] Krasner SW, Weinberg HS, Richardson SD, Pastor SJ, Chinn R, Sclimenti MJ, Onstad GD, Thruston AD, Environ. Sci. Technol., 40, 7175 (2006)

[5] Choi JH, Valentine RL, Water Res., 36, 817 (2002)

[6] Valentine RL, Brandt KI, Jafvert CT, Water Res., 20, 1067 (1986)

[7] Water Reuse Foundation, Removal and Destruction of NDMA and NDMA Precursors during Wastewater Treatment (2005) Chapter 5, 10.

[8] Lee C, Schmidt C, Yoon J, Von GU, Environ. Sci. Technol., 41, 2056 (2007)

[9] Lee C, Schmidt C, Yoon J, Von GU, Water Res., 41, 581 (2007)

[10] Andrzejewski P, Kasprzyk HB, Nawrocki J, Water Res., 42, 863 (2008)

[11] Schmidt CK, Brauch HJ, Environ. Sci. Technol., 42, 6340 (2008)

[12] Oya M, Kosaka K, Asami M, Kunikane S, Chemosphere, 73, 1724 (2008)

[13] Oya M, Kosaka K, Asami M, Kunikane S, Proceedings of 42nd Annual Conference of Japan Society on Water Environment, 2008, p. 161 (in Japanese).

[14] Oya M, Kosaka K, Asami M, Kunikane S, Proceedings of 18th Annual Conference on Ozone Science and Technology in Japan, 2008, p. 17 (in Japanese).

[15] Hollender J, Zimmermann SG, Koepke S, Krauss M, McArdell CS, Ort C, Singer H, von GU, Siegrist H, Environ. Sci. Technol., 43, 7862 (2009)

[16] Kosaka K, Asami M, Konno Y, Oya M, Kunikane S, Environ. Sci. Technol., 43, 5236 (2009)

[17] Zhao YY, Boyd J, Hrudey SE, Li XF, Environ. Sci. Technol., 40, 7636 (2006)

[18] Chen Z, Valentine RL, Environ. Sci. Technol., 40, 7290 (2003)

[19] Myers RH, Montgomery DC, A Wiley-Interscience Publication, 2002.

[20] Montgomery DC, Runger GC, Hubele NF, Engineering Statistics, John Wiley and Sons Inc., Hoboken, NJ, 2001.

[21] Vining GG, Statistical Methods for Engineers, Duxburg Press/An International Thomason Publishing, Europe/London, 2003.

[22] Parajo JC, Alonso JL, Lage MA, Vazquez D, Bioprocess Eng., 8, 129 (1992)

[23] Muthukumar M, Sargunmani D, Selvakumar N, Venkata RJ, Dyes Pigment., 63, 127 (2004)

[24] Beg Q, Sahai V, Gupta R, Process Biochem., 39, 203 (2003)

[25] Mayerhoff Z, Robert I, Franco T, Biochem. Eng. J., 18, 217 (2004)

[26] Wen ZY, Liao W, Chen SL, Bioresour. Technol., 96(4), 491 (2005)

[27] Fouillet B, Odoul M, Chambon P, Chambon R, Castegnaro M, Bull. Environ. Contam. Toxicol., 52, 681 (1994)

[28] Zulkali MMD, Ahmad AL, Norulakmal NH, Bioresour. Technol., 97(1), 21 (2006)

[29] Ravikumar K, Krishnan S, Ramalingam S, Balu K, Dyes Pigment., 72, 66 (2007)