화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.5, 2948-2957, September, 2014
DOI10.1016/j.jiec.2013.10.064  Export Citation
Hydrogen production from CO2 reforming of methane over high pressure H2O2 modified different semi-cokes
Guojie Zhang†, Jiangwen Qu, Yannian Du, Fengbo Guo1, Haixiang Zhao2, Yongfa Zhang†, and Ying Xu
  • Key Laboratory of Coal Science and Technology, Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, PR China
  • 1School of Chemical Engineering and Environment, North University of China, Taiyuan 030051, PR China
  • 2Sichuan Provincial Economic and Information Technology Commission, PR China
E-mail:,
H2O2 was used under different temperatures and pressures to activate three kinds of different semicokes. FTIR, BET, SEM and Boehm titration were used to analyze properties of the semi-cokes surfaces, finding that catalytic activities of these semi-cokes after modification by high temperature and high pressure H2O2 were improved. FTIR shows that the characteristic infrared absorption peak of functional groups on the semi-cokes surface does not change, but the absorption peak intensity of some functional groups is increased. The strength of -OH absorption peak of Hongce lignite (HCL) semi-coke at 3444 cm-1, carboxyl C=O at 1598 cm-1, aliphatic ether, cyclic ether and other organic functional groups at 1023 cm-1 in the modified Shenmu bituminous(SMB) semi-coke and Jincheng anthracite (JCA) semicoke are increased significantly. BET finds that the specific surface area and pore volume of three semicokes are increased after modification. Boehm titration shows that the basic functional group content in semi-coke is increased after modification, and the net alkali content is increased significantly. Compared with the raw semi-coke, SEM shows that the surface of semi-coke modified with H2O2 becomes rough. Modified JCA semi-coke surface pitted with holes, modified HCL and SMB semi-coke surface present porous.
Keywords:Hydrogen production;Hydrogen peroxide modification;Semi-coke;Carbon dioxide reforming of methane;Syngas
  1. Ashcroft AT, Cheetham AK, Green MLH, Vernon PDF, Nature, 352, 225 (1991)
  2. Pechimuthu NA, Pant KK, Dhingra SC, Ind. Eng. Chem. Res., 46(6), 1731 (2007)
  3. Shen J, Wang ZZ, Energy Fuels, 21(6), 3588 (2007)
  4. Yang Z, Zhang Y, Wang X, Zhang Y, Lu X, Ding W, Energy Fuels, 24, 785 (2010)
  5. Mahesh VI, New Catalysts for Syngas Production from Carbon Dioxide and Methane, West Virginia University, 2001.
  6. Zhang J, Research and Development of Nickel Based Catalyst for Carbon Dioxide Reforming of Methane, University of Saskatchewan, Saskatoon, 2008.
  7. Rostrupnielsen JR, Hansen JHB, J. Catal., 144, 38 (1993)
  8. Valderrama G, de Navarro CU, Goldwasser MR, J. Power Sources, 234, 31 (2013)
  9. Zhang Y, Zhang G, Zhang B, Feng G, Chem. Eng. J., 173, 593 (2011)
  10. Zhang G, Dong Y, Feng M, Zhang Y, Zhao W, Cao H, Chem. Eng. J., 56, 519 (2010)
  11. Zhang W, Zhang Y, Front. Chem. Eng. China, 4, 147 (2010)
  12. Guo FB, Zhang YF, Zhang GJ, Zhao HX, J. Power Sources, 231, 82 (2013)
  13. Sun H, Qu S, Wang L, Clean Coal Technol., 14, 62 (2008)
  14. Zhu Y, Cao J, Guo T, Mi J, Shanxi, Chem. Ind., 31, 7 (2011)
  15. Chareonlimkun A, Champreda V, Shotipruk A, Laosiripojana N, Fuel, 89(10), 2873 (2010)
  16. Daorattanachai P, Khemthong P, Viriya-empikul N, Laosiripojana N, Faungnawakij K, Energy Proc., 9, 515 (2011)
  17. Shen Y, Wu HY, Pan ZY, Fuel Process. Technol., 104, 281 (2012)
  18. Li C, Gao J, Feng L, Bian J, Wang P, Preparation method of semi-coke for the lowtemperature catalytic oxidation flue gas denitrification agent. China Patent:201010204883, 2010-12-22.
  19. Shen F, Shangguan J, Li C, Zhang Z, J. Taiyuan Univ. Technol., 34, 276 (2003)
  20. Blom L, Edelhausen L, van Krevelen DW, Fuel, 36, 135 (1957)
  21. Ozaki J, Nishiyama Y, Guy PJ, Perry GJ, Allardice DJ, Fuel Process. Technol., 50(1), 57 (1997)
  22. Figueiredo JL, Pereira MFR, Freitas MMA, Orfao JJM, Carbon, 37, 1379 (1999)
  23. Park SJ, Park BJ, Ryu SK, Carbon, 37, 1223 (1999)
  24. Park SJ, Jang YS, J. Colloid Interface Sci., 249(2), 458 (2002)
  25. Valdes H, Sanchez-Polo M, Rivera-Utrilla J, Zaror CA, Langmuir, 18(6), 2111 (2002)
  26. Sudibandriyo M, Pan ZJ, Fitzgerald JE, Robinson RL, Gasem EAM, Langmuir, 19(13), 5323 (2003)
  27. Boehm HP, in: Eley D, Pines H, Weisz PB (Eds.), Advances in Catalysis, Academic Press, New York, 1966, p. 179.
  28. Boehm HP, Carbon, 32, 759 (1994)
  29. Pigamo A, Besson M, Blanc B, Gallezot P, Blackburn A, Kozynchenko O, Tennison S, Crezee E, Kapteijn F, Carbon, 40, 1267 (2002)
  30. Zhang L, Study on Desulfurization of Gasoline Over Modified Activated Semi-Coke Based Adsorbents, Ocean University of China, Qingdao, 2008.
  31. Muniz J, Herrero JE, Fuertes AB, Appl. Catal. B: Environ., 18(1-2), 171 (1998)
  32. Wang C, Liu X, Yao H, Nanjing J, Univ. Chem. Technol., 22, 63 (2000)
  33. Li T, Luo S, Wu Y, Ni H, China Coal Soc., 36, 2012 (2011)
  34. Ribeiro RP, Sauer TP, Lopes FV, Moreira RF, Grande CA, Rodrigues AE, J. Chem. Eng. Data, 53(10), 2311 (2008)
  35. Fan Y, Wang B, Coal Convers, 23, 26 (2000)
  36. Hou F, Tong M, Chen M, Guangdong Ind., 37, 66 (2010)
  37. Xing D, Yan W, Proc. CSEE, 28, 14 (2008)
  38. Huang Z, Kang F, Hao J, Carbon, 121, 23 (2005)
  39. Shen W, Zheng J, Carbon Tech., 22, 5 (2002)
  40. Pang Z, Meng Q, Cao B, J. Beijing Univ. Chem. Technol., 38, 32 (2011)
  41. Williams PT, Reed AR, J. Anal. Appl. Pyrolysis, 70, 563 (2003)
  42. Xie X, Wang J, Carbon, 2, 19 (1986)
  43. Zhao B, Han W, Huo C, Liu H, Chem. Online, 67, 1 (2004)
  44. Feng Y, Huang L, Chu W, J. China Coal Soc., 36, 2080 (2011)
  45. Wu G, Sun X, Zhang Q, J. Zhejiang A&F Univ., 28, 955 (2011)
  46. Tamon H, Kazaki M, Carbon, 34, 741 (1996)
  47. Zhang Y, 23rd Annual International Pittsburgh Coal Conference, Pittsburgh, PA, United States, 2006.
  48. Harnden P, Joffe JK, Jones WG, Germ Cell Tumours V, 1st ed., Springer, London, 2002.
  49. Tian F, Zhang Y, Li C, China Coal, 2, 77 (2011)