화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.20, No.5, 2964-2968, September, 2014
Photocatalytic degradation of Brilliant Red M5B using four different nanocomposites (ZnFe2O4, porous ZnFe2O4, ZnFe2O4.TiO2, FeTiO3) coated on glass
E-mail:
This paper presents the preparation, characterization, and application of four different nanocomposites in photocatalytic degradation of the Brilliant Red M5B as a dye contaminant. Nanocomposites include ZnFe2O4, porous ZnFe2O4, ZnFe2O4-TiO2, and FeTiO3 prepared and coated on a glass slide by doctor blade method. Different techniques to characterize composites are X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and diffuse reflectance spectra (DRS). FESEM shows that nanocomposites are nanocrystallines and a narrow dispersion in size. XRD confirms that the prepared nanocomposites are composed of ZnFe2O4, FeTiO3 and TiO2. Degradation efficiency of composites is evaluated using Brilliant Red M5B as a model pollutant under UV irradiation with homemade photocatalytic apparatus. The results showed that the photocatalytic efficiency of ZnFe2O4-TiO2 is higher than that of other photocatalyst, which is mainly ascribed to ZnFe2O4 NPs with the spinel structure.
  1. Casbeer E, Sharma VK, Li XZ, Sep. Purif. Technol., 87, 1 (2012)
  2. Chen SF, Zhao W, Liu W, Zhang HY, Yu XL, Chem. Eng. J., 155(1-2), 466 (2009)
  3. Shifu C, Wei Z, Wei L, Huaye Z, Xiaoling Y, Yinghao C, J. Hazard. Mater., 172(2-3), 1415 (2009)
  4. Dutta PK, Pehkonen SO, Sharma VK, Ray AK, Environ. Sci. Technol., 39, 1827 (2005)
  5. Saratale RG, Gandhi SS, Purankar MV, Kurade MB, Govindwar SP, Oh SE, Saratale GD, J. Biosci. Bioeng., doi.org/10.1016/j.jbiosc.2012.12.009 (2012)
  6. Chang JS, Chou C, Lin Y, Ho J, Hu TL, Water Res., 35, 2841 (2001)
  7. Saratale RG, Saratale GD, Chang JS, Govindwar SP, J. Chin. Inst. Chem. Eng., 42, 138 (2011)
  8. Valenzuela MA, Bosch P, Jimenez-Becerrill J, Quiroz O, Paez AI, J. Photochem. Photobiol. A-Chem., 148, 177 (2002)
  9. Zhang L, Zhou XY, Guo XJ, Song XY, Liu XY, J. Mol. Catal. A-Chem., 335(1-2), 31 (2011)
  10. Zhang H, Chen G, Bahnemann DW, J. Mater. Chem., 19, 5089 (2009)
  11. Habibi MH, Sheibani R, J. Ind. Eng. Chem., 19(1), 161 (2013)
  12. Habibi MH, Mikhak M, Appl. Surf. Sci., 258(18), 6745 (2012)
  13. Habibi MH, Sheibani R, J. Adv. Oxid. Technol., 13, 192 (2010)
  14. Habibi MH, Mikhak M, Curr. Nanosci., 7
  15. Habibi MH, Mokhtari R, J. Sol-Gel Sci. Technol., 59, 352 (2011)
  16. Habibi MH, Zendehdel M, J. Inorg. Organomet. Polym., 21, 634 (2011)
  17. Habibi MH, Zendehdel M, Curr. Nanosci., 6, 642 (2010)
  18. Habibi MH, Askari E, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.01.003 (2013)
  19. Habibi MH, Askari E, J. Ind. Eng. Chem., 111, 227 (2013)
  20. Li Z, Lai X, Wang H, Mao D, Xing C, Wang D, J. Phys. Chem. C, 113, 2792 (2009)
  21. Tsukada M, Abe K, Yonemochi Y, Arneyama A, Kamiya H, Kambara S, Moritomi H, Uehara T, Powder Technol., 180(1-2), 232 (2008)
  22. Zhang G, Li C, Cheng F, Chen J, Sens. Actuators B-Chem., 120, 403 (2007)
  23. Kamble RB, Mathe VL, Sens. Actuators B-Chem., 131, 205 (2008)
  24. Liu Z, Zhao Z, Miyauchi M, J. Phys. Chem. C, 113, 17132 (2009)
  25. Li Z, Mi LW, Chen WH, Hou HW, Liu CT, Wang HL, Zheng Z, Shen CY, CrystEngComm, 14, 3965 (2012)
  26. Hung ST, Chang CJ, Hsu MH, J. Hazard. Mater., 198, 307 (2011)
  27. Diamanti MV, Ormellese M, Marin E, Lanzutti A, Mele A, Pedeferri MP, J. Hazard. Mater., 186(2-3), 2103 (2011)
  28. Baek MH, Jung WC, Yoon JW, Hong JS, Lee YS, Suh JK, J. Ind. Eng. Chem., 19(2), 469 (2013)
  29. Lee YC, Yang JW, J. Ind. Eng. Chem., 18(3), 1178 (2012)
  30. Hou Y, Li X, Zhao Q, Quan X, Chen G, Environ. Sci. Technol., 44, 5098 (2010)
  31. Habibi MH, Habibi AH, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.04.025 (2013)
  32. Lu D, Zhang Y, Lin S, Wang L, Wang C, J. Alloy. Compd., 579, 336 (2013)
  33. Tahir AA, Wijayantha KGU, Mazhar M, McKee V, Thin Solid Films, 518(14), 3664 (2010)
  34. Valenzuela MA, Bosch P, Jimenez-Becerrill J, Quiroz O, Paez AL, J. Photochem. Photobiol. A-Chem., 148, 177 (2002)
  35. Nikolic MV, Slankamenac MP, Nikolic N, Sekulic DL, Aleksic OS, Mitric M, Ivetic T, Pavlovic VB, Nikolic PM, Sci. Sintering, 44, 307 (2012)
  36. Yu JG, Xiong JF, Cheng B, Liu SW, Appl. Catal. B: Environ., 60(3-4), 211 (2005)
  37. Konstantinou IK, Albanis TA, Appl. Catal. B: Environ., 49(1), 1 (2004)
  38. Lachheb H, Puzenat E, Houas A, Ksibi M, Elaloui E, Guillard C, Herrmann JM, Appl. Catal. B: Environ., 39(1), 75 (2002)
  39. Puangpetch T, Sreethawong T, Yoshikawa S, Chavadej S, J. Mol. Catal. A-Chem., 287(1-2), 70 (2008)
  40. Wang C, Wang X, Xu BQ, J. Photochem. Photobiol. A-Chem., 168, 47 (2004)
  41. Mishra D, Senapati KK, Borgohain C, Perumal A, J. Nanotechnol., http://dx.doi.org/10.1155/2012/323145, 323145 (2012)