화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.5, 3453-3460, September, 2014
DOI10.1016/j.jiec.2013.12.034  Export Citation
Aggregational behavior of alkanediyl-α, ω-bis(tetradecyldimethylammonium) dibromide series with ionic and nonionic hydrotropes at different temperatures
A.J. Khanam, M.S. Sheikh†, I.A. Khan, and Kabir-ud-Din
  • Department of Chemistry, Aligarh Muslim University, Aligarh 202002, India
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The purpose of the present study was to determine the influence of various additives on the aggregation behavior of gemini surfactants and to search for means which reduce the values of critical micelle concentration. The mixed micellar properties of cationic hydrotropes (aniline hydrochloride, paratoluidine hydrochloride, ortho-toluidine hydrochloride), anionic hydrotropes (sodium salicylate, sodium benzoate, sodium tosylate) and nonionic hydrotropes (phenol, resorcinol, pyrogallol) with conventional alkyl tetradecylammonium bromide (TTAB) and their dimeric homologues viz., 14-s-14, (s = 4, 5, 6) in aqueous medium have been studied using conductometric technique at four different temperatures ranging from 298.15 K to 313.15 K. The evaluated thermodynamic parameters have been discussed in detail.
Keywords:Additives;cmc;Mixed micelles;Hydrotropes;Aggregation behavior
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