화학공학소재연구정보센터
Thin Solid Films, Vol.522, 171-174, 2012
Obtaining of Ni-Mn-Ga magnetic shape memory alloy by annealing electrochemically deposited Ga/Mn/Ni layers
Ni-Mn-Ga thin films are promising candidates for MicroElectroMechanical Systems. Triple-layers of nickel, manganese, and gallium were electrodeposited from chemical solutions on to tungsten and molybdenum refractory metal substrates. These layered films were subsequently annealed at 800 to 900 degrees C to forma Ni-Mn-Ga Heusler alloy by diffusion. To evaluate the quality of the film, the magnetization of the Ni-Mn-Ga film was measured and normalized by the magnetization of nickel, yielding the relative magnetization. Due to the formation of Ni-Mn-Ga during annealing, the relative magnetization was approximately 2 times larger than the tri-layered as-plated film. These results are comparable to bulk Ni-Mn-Ga reference samples. X-ray diffraction measurements confirmed that the material was present as a mixture of L2(1)-ordered austenite as well as modulated 10 M and non modulated martensite with manganese oxide impurities. (C) 2012 Elsevier B.V. All rights reserved.