Thin Solid Films, Vol.527, 21-25, 2013
Comparison of the electrical and optical properties of direct current and radio frequency sputtered amorphous indium gallium zinc oxide films
The electrical and optical properties of direct current and radio frequency (RF) sputtered amorphous indium gallium zinc oxide (a-IGZO) films are compared. It is found that the RF sputtered a-IGZO films have better stoichiometry (In:Ga:Zn: O = 1:1:1:2.5-3.0), lower electrical conductivity (sigma<8 S/cm), higher refractive index (n = 1.9-2.0) and larger band gap (E-g = 3.02-3.29 eV), and show less shift of Fermi level (Delta E-F similar to 0.26 eV) and increased concentration of electrons (Delta N-e similar to 10(4)) in the conduction band with the reduction concentration of oxygen vacancy (V-O). Although a-IGZO has intensively been studied for a semiconductor channel material of thin film transistors in next-generation flat panel displays, its fundamental material parameters have not been thoroughly reported. In this work, the work function (phi) of a-IGZO films is tested with the ultraviolet photoelectron spectroscopy. It is found that the phi of a-IGZO films is in the range of 4.0-5.0 eV depending on the V-O. (C) 2012 Elsevier B. V. All rights reserved.
Keywords:Amorphous indium gallium zinc oxide;Direct current sputtering;Radio-frequency sputtering;Oxygen vacancy;Fermi level;Work function