Thin Solid Films, Vol.547, 202-206, 2013
Field-emission performance and structural change mechanism of multiwalled carbon nanotubes by oxygen plasma treatment
Multiwalled carbon nanotube (MWCNT) arrays were synthesized by thermal chemical vapor deposition. To investigate the effect of O-2 plasma on the properties of the field-emission, MWCNT arrays were exposed to O-2 plasma. Field-emission properties, such as emission current and stability, were greatly improved after the O-2 plasma treatment. The O-2 plasma could remove the entangled thin MWCNTs and etch the tips of MWCNTs, leading to reduced density and sharpened tips. The analytical estimation extracted from the Fowler-Nordheim plot supports the observation of sharpening the tips of nanotubes with little change of the work function of nanotubes. (C) 2013 Elsevier B. V. All rights reserved.