Journal of Colloid and Interface Science, Vol.225, No.1, 204-208, 2000
Diffuse double-layer interaction between two identical spherical colloidal particles
A simple method is given for calculating the potential energy of the diffuse double-layer interaction between two identical spherical colloidal particles in a symmetrical electrolyte solution with the help of Dejaguin's approximation. This method uses accurate analytic expressions for the corresponding interaction energy between two parallel similar plates obtained previously (Colloids Surf A Physicochem. Eng. Asp. 146, 213 (1999); J. Colloid Interface Sci. 212, 130 (1999)). Agreement with numerical data provided by Honig and Mul (J. Colloid Interface Sci. 36, 258 (1971)) is excellent particularly for small particle separations,