The internal surface structures of silica aerogel particles synthesized using different catalysts in emulsion and microemulsion media have been investigated by means of Nz adsorption and desorption isotherms, Surface fractal dimensions have been computed using different methods: Frankel-Halsey-Hill plots of the adsorption isotherms, the thermodynamic fractal isotherm equation, and a modification of the thermodynamic fractal isotherm equation. Silica aerogels synthesized in emulsion media with an acidic catalyst have a high specific surface area without micropores and show two separate ranges of scales where the surface fractal dimensions are different and constant, Silica aerogels synthesized in emulsion media with a basic catalyst have a moderate specific surface area with a high percentage of micropores and show constant surface fractal dimensions over a larger range, Silica aerogels synthesized in microemulsion media with a basic catalyst have a low specific surface area with a moderate percentage of micropores and show a moderate range of scales over which the surface fractal dimension is constant. Analyses by both the thermodynamic and modified thermodynamic methods give similar ranges of the surface fractal dimensions of the silica particles.