화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.6, 4215-4223, November, 2014
DOI10.1016/j.jiec.2014.01.023  Export Citation
Sucrose-mediated sol-gel synthesis of nanosized pure and S-doped zirconia and its catalytic activity for the synthesis of acetyl salicylic acid
Ali Majedi, Fatemeh Davar1, †, and Alireza Abbasi
  • School of Chemistry, College of Science, University of Tehran, Tehran, Islamic Republic of Iran
  • 1Department of Chemistry, Isfahan University of Technology, Isfahan, Islamic Republic of Iran
E-mail:
Nano-sized pure and S-doped zirconia was prepared by the sol-gel method in the presence of sucrose and zirconium(IV) acetylacetonate (Zr(acac)4) as a gelation agent and Zr4+ source, respectively. Acid catalyst activity of samples was tested for the production of acetyl salicylic acid from salicylic acid and acetic anhydride as precursors, The yield (64.0%) of acetylsalicylic acid was obtained from 50 mg of S-doped zirconia calcined at 550 ℃ and after a 3 h reaction, was comparably higher than the yield of the reaction (13.3%) in the absence of a catalyst and under the same reaction condition.
Keywords:Sol-gel;Zirconia;Zirconia;Nanoparticle;Acetyl salicylic acid;Heterogeneous catalyst
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