화학공학소재연구정보센터
Korean Journal of Materials Research, Vol.23, No.2, 116-122, February, 2013
실리콘 기판 표면 형상에 따른 반사특성 및 광 전류 개선 효과
Effect of Surface Microstructure of Silicon Substrate on the Reflectance and Short-Circuit Current
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For fabricating silicon solar cells with high conversion efficiency, texturing is one of the most effective techniques to increase short circuit current by enhancing light trapping. In this study, four different types of textures, large V-groove, large U-groove, small V-groove, and small U-groove, were prepared by a wet etching process. Silicon substrates with V-grooves were fabricated by an anisotropic etching process using a KOH solution mixed with isopropyl alcohol (IPA), and the size of the Vgrooves was controlled by varying the concentration of IPA. The isotropic etching process following anisotropic etching resulted in U-grooves and the isotropic etching time was determined to obtain U-grooves with an opening angle of approximately 60o. The results indicated that U-grooves had a larger diffuse reflectance than V-grooves and the reflectances of small grooves was slightly higher than those of large grooves depending on the size of the grooves. Then amorphous Si:H thin film solar cells were fabricated on textured substrates to investigate the light trapping effect of textures with different shapes and sizes. Among the textures fabricated in this work, the solar cells on the substrate with small U-grooves had the largest short circuit current, 19.20 mA/cm2. External quantum efficiency data also demonstrated that the small, U-shape textures are more effective for light trapping than large, V-shape textures.
  1. Leendertz C, Stangl R, Schulze TF, Schmidt M, Korte L, Phys. Status Solidi C, 7, 1005 (2010)
  2. Kim SK, Lee JC, Park SJ, Kim YJ, Yoon KH, Sol. Energy Mater. Sol. Cells, 92(3), 298 (2008)
  3. Kang MG, Tark SJ, Lee J, Kim CS, Jung DY, Lee JC, Yoon KH, Kim D, Korean J. Mater. Res., 21(2), 120 (2011)
  4. Edwards M, Bowden S, Das U, Burrows M, Sol. Energy Mater. Sol. Cells, 92(11), 1373 (2008)
  5. Kim YJ, Cho JS, Lee JC, Wang JS, Song JS, Yoon KH, Korean J. Mater. Res., 19(5), 245 (2009)
  6. Zubel I, Rola K, Kramkowska M, Sens. Actuators A, 171, 436 (2011)
  7. Zubel I, Kramkowska M, Sens. Actuators A, 101, 255 (2002)
  8. Iencinella D, Centurioni E, Rizzoli R, Zignani F, Sol. Energy Mater. Sol. Cells, 87(1-4), 725 (2005)
  9. Park H, Lee JS, Kwon S, Yoon S, Lim H, Kim D, J. Kor. Inst. Met. & Mater., 46, 835 (2008)
  10. Bean KE, IEEE Trans. Electron Dev., 25, 1185 (1978)
  11. Kim JM, Kim YK, Sol. Energy Mater. Sol. Cells, 81(2), 239 (2004)
  12. Fesquet L, Olibet S, Damon-Lacoste J, De Wolf S, Hessler-Wyser A, Monachon C, Ballif C, in Proceedings of the 34th IEEE PVSC(Philadelphia, PA, June 2009) p.754 (2009)
  13. Tsunomura Y, Yoshimine Y, Taguchi M, Baba T, Kinoshita T, Kanno H, Sakata H, Maruyama E, Tanaka M, Sol. Energy Mater. Sol. Cells, 93(6-7), 670 (2009)
  14. Mueller T, Schwertheim S, Mueller N, Meusinger K, Wdowiak B, Grewe O, Fahrner W, in Proceedings of the 35th IEEE PVSC(Honolulu, HI, June 2010) p. 683. (2010)
  15. Kang MG, Tark S, Lee JC, Son CS, Kim D, J. Cryst. Growth, 326(1), 14 (2011)
  16. Maruyama T, Bandai J, Osako S, Sol. Energy Mater. Sol. Cells, 64, 261 (2000)
  17. Ge J, Ling ZP, Wong J, Mueller T, Aberle AG, Energy Procedia, 15, 107 (2012)
  18. Das UK, Burrows MZ, Lu M, Bowden S, Birkmire RW, Appl. Phys. Lett., 92, 063504 (2008)