화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.32, No.2, 268-273, February, 2015
DOI10.1007/s11814-014-0238-5  Export Citation
Catalytic ozonation of methylene blue in aqueous solution by loading transition metal(Co/Cu/Fe/Mn) on carbon
Fu Huang, Minghan Luo1, Longzhe Cui, and Guiping Wu†
  • Key Laboratory of Catalysis and Materials Science of Hubei Province, College of Chemical and Material Science, South-Central University for Nationalities, Wuhan, Hubei Province 430074, P. R. China
  • 1State Key Laboratory of Urban and Regional Ecology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China, Korea
E-mail:
Activated carbon(AC) was prepared using brewing yeast as a precursor by chemical activation; meanwhile, cobalt, copper, ferrum and manganese supported on activated carbon(Co/AC, Cu/AC, Fe/AC, Mn/AC) were prepared by adsorption-activation method. The characterizations of prepared AC, Co/AC, Cu/AC, Fe/AC, Mn/AC and their performance as ozonation catalysts were tested. The total BET surface areas of prepared AC, Co/AC, Cu/AC, Fe/AC, Mn/AC were found to be 957.7, 789.7, 485.3, 486.1 and 529.8m2/g. Absorption capacities of methylene blue (MB) were determined to 407.77, 206.52, 121.25, 123.01, 170.94mg/g, respectively. The presence of AC was advantageous for TOC reduction of MB compared with UV/O3 system, and metal Co, Cu, Fe, Mn play an important role in the degradation process. The greatest TOC removal efficiency was obtained in the presence of Co/AC.
Keywords:Catalytic Ozonation;Activated Carbon;Transition Metal;Adsorption;Methylene Blue
  1. Bhattacharyya K, Sharma A, Dyes Pigm., 65, 51 (2005)
  2. Vargas AMM, Cazetta AL, Kunita MH, Silva TL, Almeida VC, Chem. Eng. J., 168(2), 722 (2011)
  3. Goncalves M, Guerreiro MC, de Oliveira LC, de Castro CS, J. Environ. Manage., 127, 206 (2013)
  4. Gupta VK, Pathaniac D, Agarwal S, Singh P, J. Hazard. Mater., 243, 179 (2012)
  5. Le HA, Linh LT, Chin S, Jurng J, Powder Technol., 225, 167 (2012)
  6. Wu G, Jeong TS, Won CH, Cui L, Korean J. Chem. Eng., 27(5), 1476 (2010)
  7. Rauf MA, Meetani MA, Khaleel A, Ahmed A, Chem. Eng. J., 157(2-3), 373 (2010)
  8. Hameed BH, Lee TW, J. Hazard. Mater., 164(2-3), 468 (2009)
  9. Alvarez PM, Beltran FJ, Masa FJ, Pocostales JP, Appl. Catal. B: Environ., 92(3-4), 393 (2009)
  10. Orge CA, Orfao JJM, Pereira MFR, de Farias AMD, Fraga MA, Chem. Eng. J., 200, 499 (2012)
  11. Piche S, Grandjean BP, Iliuta I, Larachi F, Environ. Sci. Technol., 35, 4817 (2001)
  12. Corres MA, Zubitur M, Cortazar M, Mugica A, J. Anal. Appl. Pyrolysis, 92, 407 (2011)
  13. Danon A, Stair PC, Weitz E, J. Phys. Chem. C, 115, 11540 (2011)
  14. Shukla P, Sun HQ, Wang SB, Ang HM, Tade MO, Sep. Purif. Technol., 77(2), 230 (2011)
  15. Hashim SP, Sidek HA, Halimah MK, Matori KA, Yusof WM, Zaid MH, Int. J. Mole. Sci., 14, 1022 (2013)
  16. Dubal DP, Dhawale DS, Salunkhe RR, Jamdade VS, Lokhande CD, J. Alloys Compd., 492, 26 (2010)
  17. Singh SP, Chakradhar RPS, Rao JL, Karmakar B, J. Alloys Compd., 493, 256 (2010)
  18. Yan J, Wei T, Qiao WM, Shao B, Zhao QK, Zhang LJ, Fan ZJ, Electrochim. Acta, 55(23), 6973 (2010)
  19. Raj AME, Victoria SG, Jothy VB, Ravidhas C, Wollschlager J, Suendorf M, Neumann M, Jayachandran M, Sanjeeviraja C, Appl. Surf. Sci., 256(9), 2920 (2010)
  20. Zhang LL, Candelaria SL, Tian JJ, Li YW, Huang YX, Cao GZ, J. Power Sources, 236, 215 (2013)
  21. Hall K, Eagleton L, Acrivos A, Vermeulen T, Ind. Eng. Chem. Fundamentals, 5, 212 (1966)
  22. Dural MU, Cavas L, Papageorgiou SK, Katsaros FK, Chem. Eng. J., 168(1), 77 (2011)
  23. Tan IA, Ahmad AL, Hameed BH, J. Hazard. Mater., 337, 154 (2008)
  24. Tan IAW, Hameed BH, Ahmad AL, Chem. Eng. J., 127(1-3), 111 (2007)
  25. Chandra TC, Mirna MM, Sudaryanto Y, Ismadji S, Chem. Eng. J., 127(1-3), 121 (2007)
  26. Foo KY, Hameed BH, Chem. Eng. J., 170(1), 338 (2011)
  27. Reddy KSK, Al Shoaibi A, Srinivasakannan C, New Carbon Mater., 27, 344 (2012)
  28. Foo KY, Hameed BH, Bioresour. Technol., 104, 679 (2012)
  29. Tsai WT, Chang CY, Lin MC, Chien SF, Sun HF, Hsieh MF, Chemosphere, 45, 51 (2001)
  30. Hameed BH, Din ATM, Ahmad AL, J. Hazard. Mater., 141(3), 819 (2007)
  31. Martin MJ, Artola A, Balaguer MD, Rigola M, Chem. Eng. J., 94(3), 231 (2003)
  32. Namasivayam C, Kavitha D, Dyes Pigm., 54, 47 (2002)
  33. Guzman-Perez CA, Soltan J, Robertson J, Sep. Purif. Technol., 79(1), 8 (2011)
  34. Chen YH, Chang CY, Chen CC, Chiu CY, Yu YH, Chiang PC, Chang CF, Ku Y, Ind. Eng. Chem. Res., 43(9), 1932 (2004)
  35. Staehelin J, Hoigne J, Environ. Sci. Technol., 16, 676 (1982)