화학공학소재연구정보센터
Korean Journal of Materials Research, Vol.19, No.6, 313-318, June, 2009
Low Temperature Annealing Effect of PFO-Poss Emission Layer on the Properties of Polymer Light Emitting Diodes
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Polymer Light Emitting Diodes (PLEDs) with an ITO/PEDOT:PSS/PVK/PFO-poss/LiF/Al structure were prepared on plasma-treated ITO/glass substrates using spin-coating and thermal evaporation methods. The annealing effects of the PFO-poss film when it acts as the emission layer were investigated by using electrical and optical property measurements. The annealing conditions of the PFO-poss emission film were 100 and 200 oC for 1, 2 and 3 hours, respectively. The luminance increased and the turn-on voltage decreased when the annealing temperature and treatment time increased. After examining the Luminance-Voltage (L-V) properties of the PLED, the maximum luminance was found to be 1497 cd/m2 at 11 V for the device when it was annealed at 200 oC for 3 hours. The peak intensity of the PLED emission spectra at approximately 525 nm in wavelength increased when the annealing temperature and time of the PFO-poss film increased. These results suggest that the light emission color shifted from blue to green.
  1. Tang CW, Vanslyke SA, Appl. Phys. Lett., 51, 913 (1987)
  2. Jang JG, Shin SJ, Kang EJ, Kim HW, Chang HJ, Oh MH, Kim YS, Lee JY, Gong MS, Lee YK, Korean J. Mater. Res., 16(4), 253 (2006)
  3. D'Andrade BW, Holmes RJ, Forrest SR, Adv. Mater., 16(7), 624 (2004)
  4. Mazzeo M, Pisignano D, Della Sala F, Thompson J, Blyth RI, Gigli G, Sotgiu G, Barbareiia G, Appl. Phys. Lett., 82, 334 (2003)
  5. Zhang HA, Li Y, Jiang Q, Xie MG, Peng JB, Cao Y, J. Mater. Sci., 42(12), 4476 (2007)
  6. Kim TH, Park JH, Lee TW, Park OO, Polymer, 45(25), 8567 (2004)
  7. Lee TW, Park OO, Appl. Phys. Lett., 77, 3334 (2000)
  8. Ko SW, Jung BJ, Cho NS, Shim HK, Kor. Chem. Soc., 23(9), 1235 (2003)
  9. Bender M, Seelig W, Daube C, Frankenberger H, Ocker B, Stollenwerk J, Thin Solid Films, 326(1-2), 72 (1998)
  10. Xu Y, Peng J, Mo Y, Hou Q, Cao Y, Appl. Phys. Lett., 86, 163502 (2006)
  11. Xu Y, Peng J, Jiang J, Wu W, Yang W, Cao Y, Appl. Phys. Lett., 87, 193502 (2005)
  12. Jaeger RC, Modular Series Vol V, 2nd Edition, Prentice Hall Inc, 21 (2002). (2002)
  13. Park JY, Kim HS, Lee DH, Kwon KH, Yeom GY, Surface and Coating Tech., 131, 247 (2000)
  14. Chan IM, Hong FCN, Thin Solid Films, 444(1-2), 254 (2003)
  15. Shin SB, Gong SC, Jang JK, Gong MS, Chang YC, Sun YB, Chang HJ, J. Appl. Polym. Sci., 110(6), 3678 (2008)
  16. Lussem G, Wendorff JH, Polym. Adv. Tech., 9, 443 (1998)
  17. Zhao W, Cao T, White JM, Adv. Funct. Mater., 14(8), 783 (2004)
  18. Gupta D, Deepak KM, Optical Materials, 28, 295 (2006)
  19. Shi Y, Liu J, Yang Y, J. Appl. Phys., 87, 4254 (2000)