제주 남서부지역 스코리아의 철 화합물에 대한 미시적 연구

최원준; 고정대; Won Jun Choi; Jeong Dae Ko

Korean Journal of Materials Research, Vol.18, No.3, 143-147, March, 2008

DOI10.3740/MRSK.2008.18.3.143 Export Citation

제주 남서부지역 스코리아의 철 화합물에 대한 미시적 연구

Microscopic Study of Fe Compounds Containing Scoria in the South Western Area of Jeju

최원준, 고정대^†

제주대학교 물리학과, 제주시 아라1동 1번지

Won Jun Choi, and Jeong Dae Ko^†

Department Of Physics, Cheju National University, #1, Ara-1 Dong, Jeju-si, 690-756, Korea

E-mail:

Fe compounds in scoria as distributed in the south-western area of Jeju Island were investigated using X-ray fluorescence spectroscopy, X-ray diffractometry, and 57Fe Mossbauer spectroscopy. The samples were prepared from four parasite volcanoes. It was found that these samples are typical basalt comprised of SiO2, Al2O3, Fe, and silicate minerals. The Mossbauer spectra showed doublets for olivine, pyroxene, and ilmenite as well as sextets for hematite and magnetite. The valence state of Fe is chiefly a 3+ charge state with a slight 2+ charge state. It is expected that these results will add to the body of information related to the formation mechanisms of Jeju Island.

Keywords:scoria;XRD;XRF;Mossbauer;iron compound

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[2] Oh DI, Thesis PD (in Korean), pp. 12-18, Cheju National Univ., Jeju, (2004). (2004)

[3] Lee SW, Suh SH, J. Arch. Inst. Korean, 9(1), 403 (1989)

[4] Nakamula S, The Globe, (Chikyu), 4, 325 (1925)

[5] Choi SH, Lee JI, Park CH, Moutte J, The Island Arc., 11(4), 221 (2002)

[6] Hamm SY, Cheong JY, Jang S, Jung CY, Kim BS, J. Hydrology, 310, 111 (2005)

[7] Murad E, Hyperfine Interactions, 111, 251 (1998)

[8] Stevens JG, Khasanov A, Miller JW, Pollak H, Li Z, Hyperfine Interactions, 117, 71 (1998)

[9] Genin JMR, Bourrie G, Trolard F, Abdelmoula M, Jaffrezic A, Refait P, Maitre V, Humbert B, Herbillon A, Environ. Sci. Technol., 32(8), 1058 (1998)

[10] De Grave E, Eeckhout SG, McCammon CA, Hyperfine Interactions, 122, 21 (1999)

[11] Rusanov V, Gilson RG, Lougear A, Trauwein AX, Hyperfine Interactions, 128, 353 (2000)

[12] Marchetti SG, Spretz R, Ulla MA, Lombardo EA, Hyperfine Interactions, 128, 453 (2000)

[13] Kam SK, Hyun SS, Lee MG, J. Kor. Soc. Environ. Eng., 24(1), 57 (2002)

[14] Choi WJ, Ko JD, Sae Mulli, 55(6), 477 (2007)

[15] Choi WJ, Ko JD, J. Kor. Mag. Soc., 17(5), 1 (2007)

[16] Tatsumi Y, Shukuno H, Yoshikawa M, Chang Q, Sato K, Lee MW, J. Petrology, 46(3), 523 (2005)

[17] Gung JG, Lee JM, The Study of Igneous Rocks, pp. 64-69, Sigma Press, Seoul, (2000). (2000)

[18] Kodama H, Mckeague JA, Tremblay RJ, Gosslin JR, Townsend MG, Can. J. Earth Sci., 14(1), 1 (1977)

[19] Cullity BD, Elements of X-ray Diffraction, pp. 281-292, Addition-Wesley, (1978). (1978)

[20] Childs CW, Matsye M, Toshinaga N, Soil Sci. Plant. Nutr., 2(37), 299 (1991)

[21] Bhide VG, Mossbauer Effect and Its Application, pp. 273-274, Tata Mcgraw-Hill, New Deli, (1973). (1973)

[22] Lee CS, Lee CY, J. Kor. Mag. Soc., 7(5), 232 (1997)

[23] Long GJ, Mossbauer Spectroscopy Applied to Magnetism and Materials Science, pp. 132-153, Plenum Press, New Work, (1993). (1993)

[24] Hong SR, Hyperfine Interactions, 57, 2221 (1990)

[25] Da Costa GM, Da Silva EG, De J. Filho MF, Hyperfine Interactions, 67, 501 (1991)

[26] Zhang YS, Kim YH, Song KC, Kor. J. Soil Sci., 35(3), 145 (2002)